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Proeutectic crystallisation in hypereutectic silumins modified with Al-CuP-Me master alloys

Piątkowski J.

Archives of Foundry Engineering

2009

Vol. 9, iss. 4

195-198

Using thermal analyses TA and ATD, within a narrow range of the crystallisation period, i.e. until reaching an equilibrium temperature, the occurrence of exothermic effect was stated. Most probably, the said effect is due to a proeutectic crystallisation of \alfa phase or of \beta phase crystals. The said effect was observed to occur only in alloys after the process of modification with an addition of high-melting point elements. Complex inoculants of Al-CuP-Me (Me = Mo, Co, Cr, Nb, TiB, W) type cause hardening of silumins, due to the formation of new phases of the AlxMey type, which can act as substrates for the nucleation of \alfa dendrites and crystals of \beta phase. The experiments carried out on castings solidifying with different rates of heat transfer have proved that proeutectic crystallisation does not occur when free solidification conditions (microspheres) are provided. This fact can be related to the heat transfer rate.