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A new polyphosphazene-based catalyst for the oxidation of alkenes

Burczyk A., Pielichowski J., Bogdał D.

Polish Journal of Chemical Technology

2003

Vol. 5, nr 3

96-97

In the current work we present synthesis of novel polymeric catalysts and oxidation reactions that represent their catalytic properties. As a support polyphosphazenes were used. The structures of these compounds were investigated by means of IR, EA, 'H NMR, TGA. Oxidation reactions of alkenes were carried out on synthesized polyphosphazene catalyst at atmospheric pressure in the presence of molecular oxygen. Epoxides and ketones were obtained as main product with very high selectivity and high yields.