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2 Polish Journal of Chemical Technology

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Permeability of N, P, K-fertilizer nutrient and water vapor through PLA, PLA/PS, and PLA/HA membranes

Deng Xiaonan, Ye Sihong, Liu Kun, Li Changfeng, Liu Fangzhi, Yan Xiaoming

Polish Journal of Chemical Technology

2020

Vol. 22, nr 4

61--68

To collect permeability data and establish its database of fertilizer nutrients and water vapor through different polymer membranes for the development of polymer-coated fertilizer, the permeabilities of N-, P-, and K-nutrient from saturated aqueous of urea, NaH2PO4 and KCl solution and the permeability of water vapor through the membranes of poly lactic acid (PLA), its blends with polystyrene (PS), and its composites with humic acid (HA) particles were determined experimentally at the temperatures of 288, 298, and 308 K, respectively. The effects of the addition of PS and HA particles, temperature, and coating thickness on the permeability of fertilizer nutrient and water vapor were investigated. It was found that the addition of PS and HA increased the permeability for both the fertilizer nutrients and water vapor. The increase in temperature raised the permeability of N-, P-, and K-nutrient while decrease the permeability of water vapor in the range studied.

Permeability of P and K-nutrient through polystyrene membrane from aqueous solutions of urea + KH2PO4

Deng X., Liu K., Han X., Hu X., Zheng S.

Polish Journal of Chemical Technology

2018

Vol. 20, nr 4

113--122

With the polymer-coated fertilizer as background, the permeability of P- and K-nutrient through a representative polymer membrane-polystyrene membrane were investigated by measuring their permeability in the solutions of KH2 PO4 -water and urea-KH2 PO4 water at nominal temperature of 298 K using the Ussing chamber method. To analyze and interpret the variation of permeability with solute concentration, the solubility of permeate in polymer membrane were determined experimentally and the permeate diffusion coefficient were assessed by the measurements of density and apparent molar volume of the aqueous fertilizer solutions. An interesting “increase-decrease” trend for the permeability of both phosphorous (P)-nutrient, and potassium (K)-nutrient fertilizer with permeate concentration was observed, in which the increases in permeability at low concentrations of permeate could be attributed to the increase in solubility of KH2 PO4 in polymer while the decreases in permeability at high concentrations was due to the decrease in diffusion coefficient of permeate in polymer membrane. Finally, the release kinetics of these nutrients from a PS-coated urea-KH2 PO4 compound fertilizer granule was predicted using the Shaviv’s model along with the permeability data of P- and K-nutrient generated.