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Electrooxidation of o-Aminobenzylalcohol-Identification of Oligo-benzylether structures and Polyaniline Type Polymer by IR and UV/ViS Spectra

Boczek B., Palys B.

Polish Journal of Chemistry

2004

Vol. 78 / nr 9

1509-1521

The electrooxidation of o-aminobenzylalcohol was studied in aqueous acidic solutions. Two distinct electroactive and electrochromic products were identified by cyclic voltammetry, in situ UV/VIS and infrared spectra. In initial electrodeposition cycles the oligomers containing benzylether units are formed. Further oxidation-reduction cycles lead to the polyaniline-type polymer. Effects of the kind of acid present in the polymerization bath and of the acid concentration were also studied.