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Content available remote Study on PLA/PA11 Bio-Based Toughening Melt-Blown Nonwovens
EN
With aim to improve the mechanical and thermal properties of poly (lactic acid) (PLA) melt-blown nonwovens (MBs), polyamide 11 (PA11) was melt blended with PLA at the weight proportions of PLA/PA11 (95/5, 90/10, 85/15, 80/20), and the corresponding PLA/PA11 MBs were also manufactured. The crystallization, thermal and rheological behaviors of PLA/PA11 blends were investigated. PLA/PA11 MBs were also characterized by morphology and mechanical properties. The results indicated that PA11, as globular dispersed phases, formed confined crystals and could improve the thermal stability of PLA matrix. The viscosity of PLA/PA11 blends was slightly increased but the rheological behaviors of “shear-thinning” kept unchanged in comparison with PLA. The average diameter of PLA/PA11 MB fibers was slightly increased, whereas the toughness of PLA/PA11 MBs including the strength and elongation were efficiently enhanced compared with those of PLA MBs.
EN
This paper discusses the possibilities of obtaining polylactide-based composites and nanocomposites modified with carbon materials using the extrusion method, as well as the potential of their application in 3D printing technology. The aim of this research is to determine the impact of the presence of carbon additives on the properties of composites: mechanical, thermal and chemical. For this purpose, several research techniques were used such as scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), DSC/TG analysis, infrared Fourier-transform infrared spectroscopy (FTIR) and mechanical tests. It has been shown that it is possible to effectively produce composite materials based on PLA and carbon modifiers after optimization of the extrusion and printing process. Special attention should be paid to the quality of carbon phases homogenization in PLA matrix because the inappropriate dispersion may have a negative effect on the final properties of the composite, especially those modified with nanomaterials. Moreover, the reinforcing effect of carbon phases can be observed, and the quality of obtained filament with carbon fiber after recycling does not differ significantly from the quality of commercially available filaments. The obtained filament was successfully used to print three-dimensional scaffolds. Therefore, both the use of materials which are biodegradable and biocompatible with human tissue and the 3D printing method have the potential to be applied in tissue engineering.
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