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1 Polish Journal of Applied Chemistry

1 2001

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Development of water-soluble polymers. A survey

Bortel E., Kochanowski A., Siniarska B., Witek E.

Polish Journal of Applied Chemistry

2001

Vol. 45, nr 3-4

54-78

In this review studies on the characteristics and syntheses of water-soluble polymers are presented and discussed, which have been accomplished in the Laboratory for Polymers at the Faculty of Chemistry, Jagiellonian University, Cracow - during the past three decades. These polymers are divided into several classes on the basis of functional groups, i.e. high mol. wt. polyoxyethylenes (Mw > 106), cationic and anionic polyelectrolytes with emphasis upon chloro-ionenes, polyaddition products of aliphatic amines to epichlorohydrin or glycidol, poly(acrylic acid), as well as upon water-soluble copolymers synthesized from such monomers like maleic anhydride, vinyl ethers, 2-acrylamido-2-methyl-propylsulfonic acid (AMPS), acrylamide, olefines, vinylformamide, etc.. Derivatizations performed on polymers are discussed aimed at the formation of amphiphilic and amphoteric water-soluble resins. The cooperative phenomena of formation of wholly water-soluble intermacromolecular complexes are considered. Problems of exerting better control over radical polyreactions proceeding in aqueous solutions are also discussed.