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EN
The mechanism in which the coatings made by thermal spraying adhere to the substrate is in most cases of a mechanical nature, thus being dependent on the morphology of the substrate surface. This paper study how the texture of the substrate influences the behavior of dry sliding wear, a behavior based on the adhesion to the substrate of the analyzed coatings. For this purpose, a Co - base powder, was chosen for atmospheric plasma spraying. For the substrate, a rectangular profile made of low-alloy steel was chosen, the surface of which was textured by mechanical abrasion, in order to obtain different degrees of roughness: sample S1 - Ra1 = 1.59 µm, sample S2 - Ra2 = 2.32 µm, sample 3 - Ra3.1 = 1.25 μm, Ra3.2 = 3.88 μm. In the case of sample 3, the texturing was done on one direction, with an elongated profile, so that the effect of the main direction of dry sliding wear on the quality of the coating could be studied. The tests were performed on an Amsler test machine, at constant load, for 1 hour. The samples were mounted in a fixed position, and the wear occurred on the basis of the rotation of the metal disc, without lubrication. It was found that the coating of sample 1 was the most affected, resulting even a partial delamination, and the best behavior was recorded in the case of sample 3.1.
EN
Herein, we analyzed the morphology of atmospheric plasma-sprayed (APS) coating on medical 316L stainless steel and its influence on the physical and electrochemical properties of implant application. Five types of coatings were examined: hydroxyapatite (HAp), titanium (Ti), zirconium (Zr), Ti/HAp and Zr/HAp. The base properties of the coatings were analyzed via chemical and phase composition, surface topography, surface wettability and in particular the corrosion resistance in Ringer solution in immersed conditions and potentiodynamic test, and EIS analysis. APS coating of pure HAp on 316L stainless steel showed poor cohesive bonding to the substrate material, whereas the application of Ti and Zr interlayer prior to HAp deposition improved surface morphology and coating properties. The beneficial effect of Ti and Zr interlayer under HAp layer on binding was demonstrated. HAp containing coatings (HAp, Ti/HAp and Zr/HAp) show Ca/P ratio greater than 1.8, which may positively influence the differentiation of osteogenic cells and good adhesion to bones. Among the studied materials, the composite coatings with Zr or Zr/HAp showed favorable physicochemical properties and the highest corrosion resistance in Ringer solution.
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