Removal of water soluble Reactive Black KN-B from aqueous media by means of titanium dioxide/attapulgite (TiO2/ATP) composites was studied in a batch system. The composites were investigated using X-ray diffraction and surface area analysis. Under UV irradiation, the photocatalytic effect of TiO2/ATP composites, pH and reaction temperature on the decolorization rate of Reactive Black KN-B were investigated in detail. The adsorption experiments of TiO2/ATP composites showed that the isotherms and adsorption kinetics were well followed by the Langmuir model and the zero order equation, respectively. The maximum adsorption capacity of TiO2/ATP composites for Reactive Black KN-B calculated by the Langmuir model was 20.08 mg g-1. It can be concluded that the TiO2/ATP composites could be good photocatalysts/adsorbents for treating Reactive Black KN-B wastewater.
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Glasses showing catalytic effect have been of much interest recently because the catalytic layer is very effective in reducing of pollutants. The use of these glasses may bring reduction in cleaning costs. There are several methods of preparation of TiO2 with good catalytic properties, but sol-gel technique offers an opportunity to enhance catalytic effect by precise optimization of the composition and microstructure of the layer. This study concerns optimization of the composition and preparation technology of catalytic layers based on SiO2-TiO2 system. Catalytic effect was studied using Rhodamine B as a sensor. UV-VIS and photoelectron spectroscopy were the main research tools used in this study.
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