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Interaction of the Components in Li-V-Sn System at 470 K

Azarska O., Pavlyuk V.

Polish Journal of Chemistry

2003

Vol. 77 / nr 8

1027-1031

The isothermal section of the Li-V-Sn system at 470 K has been investigated by X-ray phase analysis. There is an unmixing region, which extends at ternary system to about 12 at. % of Sn. Two ternary phases Li11V3Sn4 and ~LiV2Sn and solid solutions based on the binary compounds were obtained. Crystal structures were determined for both ternary phases: Li11V3Sn4 is a superstructure to Li13Sn5 binary compound, and LiV2Sn crystallizes in a BiF3 structure type. The solubility of the third component in the binary compounds is less than 10 at. %.