A statistical analysis of geometrical parameters for 1-Si, 8-N-substituted naphthalenes retrieved from the CSD revealed three factors describing structural consequences of peri interactions in such derivatives. The most important of them is an in-plane deformation whichmay be estimated by a linear combination of several geometrical parameters of the naphthalene fragment. It is best approximated by values of splay angles. The second consequence is an out-of-plane deformation formally defined by all torsion angles. It is well approximated by the Si–C(1)…C(8)–N torsion angle. The third factor can be associated with substituent effects and it manifests itself mainly by changes of Car-N/Si bond lengths and their ipso angles. Similar analysis performed for a more general data set consisting of 1-X, 8-Y-disubstituted naphthalenes fully supports the above interpretation. The peri X…Y distance (PD) can be expressed as linear combinations of the factors obtained, which leads to a multiple regression line with the value of the free term very close to PD and coefficients being relative weights of particular factors. It appears that in plane deformation contributes to the d(X...Y) distance farmore significantly than the other factors.
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