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Zirconium silicates in a peralkaline granite: a record of the interplay of magmatic and hydrothermal processes (Ilímaussaq complex, Greenland)

Cegiełka Małgorzata, Bagiński Bogusław, Macdonald Ray, Belkin Harvey E., Kotowski Jakub, Upton Brian G. J.

Acta Geologica Polonica

2022

Vol. 72, no. 2

235--245

Compositional and textural data are presented for zircon, secondary Zr-silicates, catapleiite and elpidite in a peralkaline granite from the Ilímaussaq complex, south Greenland. The zircon is essentially stoichiometric, with (Zr + Hf + Si) = 1.96–1.98 a.p.f.u. The secondary Zr-silicates show a wide range of Zr/Si atomic ratios (0.13–0.79). The catapleiite varies from close to stoichiometric to a Na-depleted type showing cation deficiency (5.2–5.8 a.p.f.u.). Elpidite shows similar variations (7.2–9.0 a.p.f.u.). Textural relationships between the Zr phases are interpreted to show that magmatic zircon interacted with hydrous fluids exsolved from the magma to form the secondary Zr-silicates. Formation of catapleiite was late-magmatic, in equilibrium with a Na-Si-bearing fluid. This was followed by the crystallization of elpidite, the fluid having a different Na/Si ratio. Both catapleiite and elpidite experienced Na-loss during late-stage hydrothermal alteration.

Note on the stable isotope values of vein calcite in the El-Seboah peralkaline granite (SW Egypt)

Hassan K. M.

Mineralogia

2011

Vol. 42, iss. 2/3

113--120

Stable isotope data for carbon (δ13C) and oxygen (δ18O) are used to constrain the environments of calcite formation in two veins in the El-Seboah peralkaline granite in south-western Egypt. Vein I with calcitemagnetite-goethite-hematite-quartz, and vein II with calcite-magnetite-goethite-kaolinite-hematite-quartz are texturally distinct. The calcite of each vein has characteristic δ13C- and δ18O-values: + 0.32 and -7.28‰ for vein I and + 1.16 and - 1.21‰ for vein II, respectively. The observed differences between the δ13C values of the two veins indicate that they represent two separate systems of primary dissolved inorganic carbon formed at or near equilibrium with atmospheric CO2. The δ18O values, on the other hand, indicate calcite deposition from meteoric waters which were fresh for vein I and brackish for vein II.