In this paper, we shortly present and discuss structural, electrical and spectral properties of organic composites with the general formulae (BEDT-TTF)x/A and (BEDO-TTF)x/A, where A denotes an electron- acceptor species such as iodine, AuI, or AuI3. Electron transfer between large conducting grains restricts electrical conductivity of the composites; the most probable mechanism being fluctuation -induced tunneling conduction. Extensive spectral properties of organic composites are presented. It is shown that spectral studies can provide specific information about charge localization, electron-electron and electron-molecular vibration interactions, and about changes in the properties of highly conducting organic composites with ageing or annealing.
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