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Opoka – a mysterious carbonate-siliceous rock: an overview of general concepts

Jurkowska Agata, Świerczewska-Gładysz Ewa

Geology, Geophysics and Environment

2022

Vol. 48, no. 3

257--278

The opoka is a carbonate-siliceous marine sedimentary rock, forming a thick succession of Upper Cretaceous age in Poland and in another regions of Europe. This rock has been studied for over 150 years, but only the use of modern analytical techniques enables for the formulation of its mineralogical definition, which identifies the distinct features of opoka and allows it to be distinguished from other rocks (e.g. chalk, gaize). Parallel to the petrographic research on opoka, its palaeobathymetric interpretations, which were based on the palaeotectonic models of Danish-Polish Trough inversion has been revised. Depending on the model of palaeotectonic history, opoka has been interpreted as a deep-water or shallow facies, without detailed petrographic studies of its mineralogical composition. The paper presents various aspects of opoka, including: history of the term, nomenclature, mineralogical composition, microtexture and palaeoecological significance of Cretaceous opoka. New data which permit precise definition of this rock term, and its mineralogical composition are discussed in the light of palaeoecological reconstructions, bathymetry and existing models of opoka distribution.

The role of mineral phases in the biogas production technology

Geršl M., Kanduč T., Matýsek D., Šotnar M., Mareček J.

Ecological Chemistry and Engineering. S

2018

Vol. 25, nr 1

51--59

In the field of electric power industry, renewable energy sources, fertilisers, reclamation, and waste management, biomass is widely studied and used. Minerals are present in every step of biogas transformation, but their forms, occurrence, and composition have not been studied yet. However, there is no comprehensive study research that would address the presence of mineral phases in the process of biogas production. This aim of the study is determination of the amount and composition of the mineral phases present in fermentation residues resulting from different production technologies. Digestate mineral composition was analysed using 46 samples from agricultural biogas plants and university testing biogas reactor. The majority of samples contained the amorphous phase. Minority phases consisted of quartz, albite, orthoclase, muscovite, and amphibole. Opal-CT was found in eleven samples (1.26 to 12.1% wt.). The elements present in gas-liquid fluids or in liquids, gases and aerosols within the biogas technology system may create mineral phases, namely the amorphous phase or the crystalline phase under certain conditions. Opal-CT may enter the fermenter as part of plant tissues referred to as phytoliths, or as an unwanted admixture of different origin. It may also originate from the present amorphous SiO2.