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Kinetic of Oil Sludge Thermolysis Process in Presence of Nickel, Cobalt and Iron-Supported Microsilicate

Tyanakh Sairagul, Baikenov Murzabek, Yun Ma Feng, Khamitova Tolkyn, Balpanova Nazerke, Tulebayeva Balzhan, Kyzkenova Aikorkem, Karimova Aliya, Rakhimzhanova N.Z., Kochegina E.V.

Polish Journal of Chemical Technology

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2023

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Vol. 25, nr 3

101--109

EN

The article is devoted to the experimental determination of thermokinetic parameters of oil sludge thermal degradation using the model-free Ozawa-Flynn-Wall method in the presence of a nanocatalyst (nickel, cobalt and iron-supported microsilicate) by calculating Arrhenius kinetic parameters (activation energy and pre-exponential factor). The phase composition of the reflex microsilicate was established – 4.12; 2.51 Å – SiO2, nickel-supported microsilicate reflexes: 2.09; 1.48 Å – NiO, reflexes: 4.25 Å – SiO2 and acid numbers of microsilicate – 64 μmol/g of prepared nanocatalysts. Using the method of Brunauer, Emmett and Teller, the specific surface area of the microsilicate was established – 18.3 ± 0.3 m2 /g, the microsilicate with nickel applied – 20.9 ± 0.2 m2 /g and the adsorption isotherm of the prepared nanocatalysts (microsilicate with nickel, cobalt and iron). Thermokinetic parameters of thermal decomposition of oil sludge without a catalyst and with a catalyst at an increment of 0.9 are 99.0 and 93.3 kJ/mol nickel-supported microsilicate, 51.9 kJ/mol cobalt-supported microsilicate, 111.3 kJ/mol iron-supported microsilicate and non-metal-supported microsilicate 173.7 kJ/mol, respectively. The study of the kinetic parameters of pyrolysis of oil sludge using various catalysts makes it possible to assess their influence on the process of decomposition of organic components. The results of the experiments showed that the use of catalysts significantly affects the destruction of oil sludge. Dynamic thermal analysis at different heating rates studied the dynamics of oil sludge decomposition. The study of the effect of catalysts on the kinetic parameters of oil sludge pyrolysis is an important step in the development of new methods for the disposal of petroleum products and the reduction of their negative impact on the environment. The obtained experimental data on thermal degradation kinetics of oil sludge will find application in designing a reactor for the process of destructive hydrogenation of heavy hydrocarbon raw materials.

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Monitoring of Air Pollution in the Area Affected by the Storage of Primary Oil Refining Waste

Strizhenok Alexey V., Ivanov Andrey V.

Journal of Ecological Engineering

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2021

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Vol. 22, nr 1

60--67

EN

At present, monitoring of air pollution near industrial facilities is one of the most urgent tasks. Its implementation is a requirement of Article 42 of the Constitution of the Russian Federation and the basis for the ecological well-being of the population. This problem is especially critical for the production facilities located within residential areas or in close proximity to them. The scientific article presents the results of a monitoring study of the air pollution in a residential area exposed to the negative impact of the storage of primary oil refining waste. Within the frames of the scientific research, the analysis of the stock materials of the enterprise was conducted; field observation was performed on the territory of the considered enterprise and the construction of ecological cartographic models was carried out, reflecting the level of the air pollution in the territory under consideration. The study also carried out a literary review and presented a list of the main existing technologies for the utilization of oil sludge to improve the quality of the air in the region under consideration.

3

Szlam naftowy jako paliwo i surowiec do produkcji cementów pucolanowych

Kourdache Hayat, Adjdir Mehdi, Bendraoua Abdelaziz, Brucker Jean Michel

Cement Wapno Beton

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2020

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R. 25, nr 6

469--479

PL

Celem badań była ocena możliwości zastosowania szlamu naftowego jako alternatywnego paliwa w piecach cementowych, ponieważ 1 kg tego szlamu może zastąpić 0,82 m3 metanu. Natomiast popiół ze spalenia tego szlamu można stosować jako uboczny materiał cementowy, do produkcji cementu pucolanowego. Zbadano skład chemiczny, gęstość, powierzchnię i skład ziarnowy popiołu. Ten popiół zastosowano jako zamiennik cementu portlandzkiego, zastępując nim 5, 10, 15 i 20% cementu, stosując go do wytwarzania zapraw. Zbadano konsystencję, czas wiązania i właściwości mechaniczne tych zapraw i porównano z zaprawami bez dodatku popiołu. Dodatek popiołu zwiększył w spoiwie zawartość SiO2 i opóźnił wiązanie, w porównaniu z cementem. Zgodnie z normą EN 197 zaprawa z dodatkiem 5% popiołu, która miała maksymalną wytrzymałość wynoszącą 46 MPa po 28 dniach, należała do cementu CEMII/B 42,5N. Natomiast cement zawierający 10% i 20% popiołu został zaliczony do klasy wytrzymałości 32,5N.

EN

The aim of this study was the valorisation of oil sludge as an alternative fuel in the cement kilns since 1 kg of oil sludge can substitute 0.82 m3 of methane. The ash from oil sludge combustion can be used as secondary cementitious material, for the production of cement-based pozzolanic composites. The elemental composition, density, surface properties, and particle size distribution of the ashes were measured. Then the ashes were used along with ordinary Portland cement at different ratios of substitution: 5, 10,15, and 20% by mass to produce mortars which were tested for their normal consistency, setting time, mechanical properties, and then compared to reference mortar without ashes. According to the results, the higher SiO2 content was assigned to ash compared to cement. The incorporation of ash resulted in the retardation of the setting. According to European standard EN-197, the mortar with the addition of 5% of ash which presents a maximum strength equal to 46 MPa obtained at 28 days is classified as CEM II/B 42.5N. However, cements containing 10% and 20% of ash have been classified in strength class 32.5N.

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Identification and characterisation of oil sludge degrading bacteria isolated from compost

Ubani O., Atagana H. I., Thantsha M. S., Rasheed A.

Archives of Environmental Protection

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2016

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Vol. 42, no. 2

67--77

EN

Compounds present in oil sludge such as polycyclic aromatic hydrocarbons (PAHs) are known to be cytotoxic, mutagenic and potentially carcinogenic. Microorganisms including bacteria and fungi have been reported to degrade oil sludge components to innocuous compounds such as carbon dioxide, water and salts. In the present study, we isolated different bacteria with PAH-degrading capabilities from compost prepared from oil sludge and animal manures. These bacteria were isolated on a mineral base medium and mineral salt agar plates. A total of 31 morphologically distinct isolates were carefully selected from 5 different compost treatments for identification using polymerase chain reaction (PCR) of the 16S rRNA gene with specific primers (universal forward 16S-P1 PCR and reverse 16S-P2 PCR). The amplicons were sequenced and sequences were compared with the known nucleotides from the GenBank. The phylogenetic analyses of the isolates showed that they belong to 3 different clades; Firmicutes, Proteobacteria and Actinobacteria. These bacteria identified were closely related to the genera Bacillus, Arthrobacter, Staphylococcus, Brevibacterium, Variovorax, Paenibacillus, Ralstonia and Geobacillus. The results showed that Bacillus species were predominant in all composts. Based on the results of the degradation of the PAHs in the composts and results of previous studies on bacterial degradation of hydrocarbons in oil, the characteristics of these bacterial isolates suggests that they may be responsible for the breakdown of PAHs of different molecular weights in the composts. Thus, they may be potentially useful for bioremediation of oil sludge during compost bioremediation.