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Studies on Adsorption of Petroleum Products under Static Conditions

Sabadash Vira, Lysko Vitaliy

Journal of Ecological Engineering

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2023

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Vol. 24, nr 10

40--46

EN

This paper provides an overview of the adsorption of petroleum products, focusing on various aspects such as adsorbent types, mechanisms of adsorption, factors influencing efficiency, kinetics, equilibrium, practical applications, and environmental implications. It explores the properties and characteristics of adsorbents, including activated carbon, zeolites, clay minerals, silica gel, and others, highlighting their interaction with petroleum products. The article delves into the theories and mechanisms governing the adsorption process, discussing physical and chemical adsorption as well as the role of forces like van der Waals, hydrogen bonding, and electrostatic interactions. The results of experimental investigations were conducted to evaluate the adsorption capacities of various adsorbents for petroleum products. The adsorption performance, kinetics, and equilibrium behavior of different adsorbents were analyzed, providing insights into their effectiveness in removing petroleum contaminants from aqueous solutions. The adsorption kinetics and equilibrium studies were explored through mathematical models like Langmuir and Freundlich isotherms. The practical applications of adsorption in the petroleum industry were discussed, including removing pollutants from wastewater, gas and diesel purification, and desulfurization. The environmental implications of adsorption technology in mitigating oil spills and reducing petroleum-related pollution were addressed. The conclusion emphasizes the significance of these studies in enhancing understanding, developing efficient solutions, and addressing environmental challenges associated with the petroleum industry. Ongoing research in this field aims to further improve adsorption processes for a more effective and sustainable approach.

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The Usage of Plant Test Systems for the Determination of Phytotoxicity of Contaminated with Petroleum Products Soil

Cherniak Larysa, Mikhyeyev Oleksandr, Madzhd Svitlana, Lapan Oksana, Dmytrukha Tetyana, Korniienko Iryna

Journal of Ecological Engineering

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2021

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Vol. 22, nr 6

66--71

EN

The level of phytotoxicity of the soil samples artificially contaminated with the aviation kerosene was determined in the work. The dependences of the growth characteristics of the plant test system (flax) on the excess of the approximate permissible concentrations (APC) of the oil product concentration in the soil were identified. The change in the mass of raw material depending on the level of aviation kerosene contamination of soil samples was determined. A decrease in the plant growth activity with an increase in the content of aviation fuel in the soil was established. It was found that there is a hormesis effect at certain concentrations of aviation kerosene in the soil. The comparison of the concentration dependences of the action of petroleum products on the growth rates of seedlings and their dependence on the distance to the source of pollution allowed in the latter case to conduct a kind of “dosimetry” on exposure concentrations when the petroleum product concentration was not determined.

3

Efficiency of Sorbents Application for the Decrease of the Residual Content of Oil Products in the Industrial Waste

Tarasova Svetlana, Gaevaya Elena, Bytsko Anastasia

Journal of Ecological Engineering

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2021

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Vol. 22, nr 1

36--40

EN

Well drilling involves the formation of the bore mud in a form of drilled solids with waste drilling mud, containing oil products in its structure. Nowadays, the widely used methods such as thermal, physical and biological ones cannot be considered as complex approach to the solution of the problem of the oil refinery wastes handling. Introduction of the peat and natural mineral sorbents into the bore mud allows decreasing the residual content of the oil products, and, thus, decreasing the level of negative influence on the environment. On the basis of the conducted studies, it was revealed that different norms of sorbents and peat introduction into the bore mud decreased the concentration of oil products equally well; therefore, the recommended dosage of sorbents and peat at the low initial values of oil products can be 3–5%. When introducing glauconite in a form of flour and grain there it noted that the size of grain particles of the sorbent influenced insignificantly the decrease of oil products concentration in the bore mud. The use of natural mineral sorbents and peat favorably influences the development of plants. At the same time, the formation of viable phytocenosis with high value of phytomass of vegetative over-ground sprouts takes place.

4

Dynamics of Changes in the Concentration of Oil Products in the Tura River within the Residential Area of the Large Oil Capital of Russia

Kryakhtunov Alexander V.

Journal of Ecological Engineering

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2021

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Vol. 22, nr 11

223--229

EN

In the course of the study, the following tasks were solved: determining the level of oil products and their spatial distribution in surface waters and bottom sediments of the Tura River, studying the features of the accumulation of oil products in bottom sediments in different sections of the Tura River, as well as the effect of storm and melt water contaminated with oil products within the coastal boundaries on the general background of pollution, calculated by the approximation method the distance at which the maximum permissible concentration for the Tura River would be reached, gave recommendations on the preservation of the object under study. The research was carried out in the laboratory of the Tyumen Industrial University. The analysis of samples for the content of oil products was carried out by the fluorometric method on a fluid analyzer “Fluorat-02–2M”. The results of the study indicate the need to monitor surface waters and toughly respond to insufficient compliance with the standards for the protection of surface waters and bottom sediments within the city of Tyumen.

5

Environmental Safety of Motor Transport Enterprises within the Urban Areas

Lukianova Vitalina, Trofymchuk Oleksandr, Anpilova Yevheniia

Journal of Ecological Engineering

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2020

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Vol. 21, nr 4

231--236

EN

The water resources are the main component of technological processes occurring in industry; therefore, increasing the level of environmental safety, in particular, wastewater treatment without adverse impact on the environment and human health is relevant. The preliminary environmental analysis of the motor transport enterprise (MTE) activity has been carried out. It has been established that about twenty environmental aspects identified in the departments of technical inspection and repair and service have an adverse impact on the state of the environment. A substantial impact on the environment occurs when the sewage containing petroleum products, washing liquids, waste lubricants and contaminated by the products of tissue origin enters the soil and water objects and their resources. On the basis of the preliminary analysis, the authors have identified the environmental aspects of the company’s activity and proposed an environmental policy as an essential element for the implementation of the environmental management system. The studies conducted with the aim of determining the motor transport enterprise sewage composition revealed an excessive content of polluting chemical substances, namely: suspended substances, phosphates, iron, fats, oil products and synthetic detergents. The expediency of using carbonaceous sorbents of vegetable origin, which were obtained from the waste wood industry for wastewater treatment of the enterprise, was investigated. It was revealed that the process of sorption purification improved the quality of wastewater of the motor transport enterprise to the standard values. The proposed recommendations for the implementation of the environmental management system will gradually reduce the impact of the company on the main components of the biosphere. Effective implementation of the environmental management system will help to increase the competitiveness of the enterprise and lead to an economic effect by saving raw materials, materials, energy resources, reducing the environmental fees and penalties.

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Sozdanie otečestvennogo kompleksa „Vizir” dlâ izmerenij dvunapravlennyh spektropolârizacionnyh koèfficientov otraženiâ i ârkosti prirodnyhi iskusstvennyh obʺektov

Sizikov A. S., Beliaev Y. V., Tsykman I. M.

Bezpieczeństwo i Technika Pożarnicza

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2018

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Vol. 50, iss. 2

28--37

EN

Objective: The article provides the substantiation, reasonability and main results of developing the «Vizir» national complex for the measurement of the spectropolarization characteristics of two-directional radiant reflectivity and brightness of natural artificial objects. Its purpose, structure and main technical parameters are also given. Introduction: A complex for the measurement of the spectropolarization characteristics of two-directional radiant reflectivity and brightness of natural artificial objects was developed within the framework of the State scientific and technical programme, entitled “Standards and scientific instruments”, in 2016-2018 by employees of the Department of Aerospace Studies Institute of Applied Physical Problems of A.N. Sevchenko of Belarus State University, in cooperation with the Research Institute of Fire Safety and Emergencies. Summary: As part of the work, the literature regarding goniometric installations, used to measure bidirectional reflectance, was reviewed; the need to develop a national complex for the measurement of the spectropolarization characteristics of two-directional radiant reflectivity and brightness of natural artificial objects, provided with more advanced features as compared to the existing foreign analogues, was proven, allowing to carry out polarization measurements; preliminary results of the work connected with establishing the “Vizir” national complex for the measurement of the spectropolarization characteristics of two-directional radiant reflectivity and brightness of natural artificial objects were presented; the final structure of the developed complex was specified; and the basic technical requirements were defined. Practical implications: In relation to the activity of the Ministry of Emergency Situations of the Republic of Belarus, the “Vizir” complex makes it possible to essentially increase the abilities related to the correct and high-quality thematic processing of the received information and data; to improve the accuracy of determining the parameters of remote monitoring objects, including zones of emergency situations of natural and technology-related character to take into account the consequences of natural and man-made emergencies, as well as the consequences of the anthropogenic impact on natural objects and environmental safety; and to ensure improvements, updating and expansion of the existing base of bench measurements of the spectral, energy and geometric characteristics of aerospace remote sensing systems.

PL

Cel: W artykule przywołano uzasadnienie, celowość i główne rezultaty opracowania krajowego kompleksu „Wizir” dla pomiarów dwukierunkowych współczynników polaryzacji odbicia i luminancji obiektów naturalnych i sztucznych, a także jego przeznaczenie, skład i podstawowe parametry techniczne. Wprowadzenie: W ramach realizacji zadania „Opracowanie kompleksu dla pomiarów dwukierunkowych współczynników polaryzacji odbicia i luminancji obiektów naturalnych i sztucznych” Państwowego Naukowo-Technicznego Programu „Wzorce i przyrządy naukowe” w latach 2016–2018 pracownicy wydziału badań przestrzeni powietrznej i kosmicznej Instytucji Naukowo-Badawczej – Instytutu Fizycznych Problemów Stosowanych im. A.N. Sewczenko Państwowego Uniwersytetu Białorusi wraz z Instytutem Naukowo-Badawczym Bezpieczeństwa Pożarowego i Problemów Sytuacji Nadzwyczajnych Ministerstwa Sytuacji Nadzwyczajnych Republiki Białorusi prowadzą pomyślne opracowanie odnośnego kompleksu „Wizir”. Wnioski: W ramach przeprowadzonych prac: dokonano przeglądu zagranicznych instalacji goniometrycznych, wykorzystywanych do pomiarów dwukierunkowego współczynnika odbicia; uzasadniono konieczność opracowania krajowego modelu kompleksu do pomiarów dwukierunkowych współczynników polaryzacji odbicia i luminancji obiektów naturalnych i sztucznych z rozszerzonymi możliwościami w porównaniu z już istniejącymi zagranicznymi odpowiednikami, w tym dzięki możliwości wykorzystania polaryzacyjnych nasadek, pozwalających przeprowadzać pomiary polaryzacyjne; przytoczono wstępne rezultaty prac w kwestii utworzenia nowego krajowego kompleksu „Wizir” do pomiarów dwukierunkowych współczynników polaryzacji odbicia i luminancji obiektów naturalnych i sztucznych; wskazano ostateczny uściślony skład opracowywanego kompleksu i określono jego podstawowe wymogi techniczne. Znaczenie dla praktyki: Odnośnie działalności Ministerstwa Sytuacji Nadzwyczajnych Republiki Białorusi tworzony kompleks „Wizir” pozwala: znacząco zwiększyć możliwość przeprowadzenia poprawnego i jakościowego tematycznego opracowania otrzymywanych danych informacyjnych; zwiększyć dokładność określania parametrów obiektów zdalnego monitoringu, w tym w strefach sytuacji nadzwyczajnych o charakterze naturalnym i technogenicznym; uwzględniać skutki sytuacji nadzwyczajnych o charakterze naturalnym i technogenicznym, a także skutki antropogenicznego oddziaływania na obiekty przyrodnicze i bezpieczeństwo ekologiczne; zapewnić doskonalenie, aktualizację i poszerzenie posiadanej bazy pomiarów stanowisk spektralnych, energetycznych i geometrycznych charakterystyk systemów zdalnego sondowania przestrzeni powietrznej i kosmicznej.

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Modelling of the system for cleaning up free oil products with the application of the MARS simulator

Knez J., Knez D.

AGH Drilling, Oil, Gas

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2013

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Vol. 30, no. 2

327-332

EN

Nowadays one of the most important problems in environmental protection is the pollution of groundwater by derivative products of oil. A common case of the infiltration of the oil derivative products to the ground water system is mainly connected with accidental oil spills in various types of environmental conditions. In this case we encounter numerous types of problems connected especially with the pollution in: 1) aeration zones, 2) saturation zones. The first step is a conceptual model for the proper recognition of the type and scale of the problem. After making a conceptual model it is possible to take a preliminary decision to recognize what sort of pollution is the source of the environmental problem. A study example describes modeling of free products of oil (LNAPL) floating on the groundwater table using MARS (Multiple Areal Remediation Simulator). The multiphase model was made on the basis of theoretical model concepts. In the modeling the recovery and migration of LNAPL are simulated, and the recoverable and residual spill volumes of derivate products of oil are estimated. Modeling indicates the best location of the remediation system and the pumping wells. Additionally, modelling can be applied to manage the remediation system for improving the efficiency and for decreasing the catchment area of piezometers and wells.