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EN
The abundant availability of waste oil palm trunks is one of the potential fibers for new thermal insulation materials. While focusing on the manufacturing of thermal insulation materials, the main points to be considered are particle size, reinforcement fiber ratio, and press durations, besides binders type and temperature. This study aimed to optimize the manufacturing process of hybrid bio panels based on oil palm trunks as thermal insulation material. The response surface methodology (RSM), with a Box-Behnken Design (BBD), was used to model and optimize the manufacturing process variables. A total of 17 hybrid bio panels were in operation and the independent variables used were particle size, ramie ratio, and press duration. The dependent variables were water absorption, thickness swelling, MOR, and thermal conductivity. The hybrid bio panel obtained under the optimum conditions was characterized by thermogravimetric analysis to observe thermal stability. On the basis of analysis of variance and the contour plot, it was discovered that the interaction between particle size and ramie fiber ratio was a significant variable to optimize hybrid bio panel manufacture. The thermal resistance and modulus of rupture of hybrid bio panels also improved with higher particle size and ramie fiber ratio. The optimum manufacturing process was obtained at OPT particle size of 0.248 mm, ramie fiber ratio of 19.775, and press duration of 25 min. This condition produces a thermal conductivity of 0.079 W/mK, modulus of rupture of 17.702 MPa, water absorption of 54.428%, and thickness swelling of 21.974%. In addition, the hybrid bio panel resulted in thermal stability of 341 °C.
EN
Dyeing operations in industries like textiles, paper, and leather are significant contributors to environmental pollution due to the release of harmful dyes. The current study aimed to examine the use of oil palm trunk (OPT) treated with phosphoric acid (PAOPT) to remove malachite green (MG) dye from aqueous solutions through batch adsorption experiments. Spectroscopic and quantitative tests were used to characterise the PAOPT adsorbent. The effects of initial solution pH (3–6), PAOPT dosage (0.02–0.10 g), and adsorption duration (0–120 min) were studied. The adsorption rate of MG followed a pseudo-second-order kinetic model with a high regression correlation (R2 ) and a low chi-squared value (χ2 ). The single-layer adsorption of PAOPT for MG was determined to be 217.23 mg/g at a pH of 6, 0.02 g PAOPT mass, 20 min contact time, and 298 K. The percentage of MG desorption from the loaded PAOPT using distilled water and 0.01 M HCl was 0% and 19.65%, respectively, indicating the possible involvement of electrostatic interactions between the dye and PAOPT, π-π interaction and hydrogen bonding. The experimental results of the current study and the assessment with other stated adsorbents indicate that PAOPT could be used as a cost-effective alternative adsorbent for MG removal.
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