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1 Journal of Achievements in Materials and Manufacturing Engineering

1 2009

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Different diamonds in meteorites - DaG 868 and NWA 3140 ureilites

Karczemska A., Jakubowski T., Vergas F.

Journal of Achievements in Materials and Manufacturing Engineering

2009

Vol. 37, nr 2

292-297

Purpose: Ureilites are a rare type of meteorites containing tiny diamond grains. In our research we used two ureilites: NWA 3140 and DaG 868. The aim of this paper is to show the non-uniformity of carbon in ureilites, especially differences of ureilitic diamonds. Design/methodology/approach: One of the best methods to examine different allotropic forms of carbon is Raman Spectroscopy. This method used to investigate diamonds provides a lot of information about diamond polytypes, crystals sizes, a level of defects and internal stresses, etc. 2D imaging was done with a Confocal Raman Imaging alpha 300 R WITec apparatus equipped with an Nd:YAG laser with 532 nm excitation. The spectra were collected with a high-sensitive confocal microscope connected to a high-throughput spectrometer equipped with a CCD camera. Mean and local elemental compositions of the samples were determined by an energy dispersive X-ray (EDX) method. A scanning electron microscope HITACHI S-3000 N was used to characterize microstructures (carbon veins) of the samples. Findings: Different diamond generations were found in ureilites in the presented research with a wide range of Raman shifts from 1309 cm -1 to 1339 cm -1. Also graphite and amorphous carbon were found. Research limitations/implications: Presented research is another step to solve the problem about diamond origin in meteorites. Practical implications: Understending diamonds and the other carbon phases in meteortites could help in manufacturing new carbon materials in laboratory. Originality/value: Authors use Raman imaging to show distribution of diamonds in ureilites, this is pioneer research, results of DaG 868 and NWA 3140 are shown for the first time.