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Nonconventional Hydrogen Bonding and Vertical Electron Detachment in Anionic Complexes of Gold with DNA Bases: Few Essayistic Fragments

Kryachko E. S.

Polish Journal of Chemistry

2009

Vol. 83, nr 5

917-931

The present work performs the computational Gedanken experiments on an ion photo-electron spectroscopy for the complexes [Au-DNA base]– established between the auride anion Au- and the DNA bases thanks to the nonconventional hydrogen bond where Au- casts as the nonconventional proton acceptor. The fascinating phenomenon of the proton acceptor character of Au- to form a variety of nonconventional hydrogen bonds with the DNA bases is computationally unveiled in the present work which also shed a light on the mechanism of the vertical electron detachments of [Au-DNA base]– and their further access of the ground electronic states of the neutral parent hood complexes [Au-DNA base].