Wyniki wyszukiwania - BazTech

Ograniczanie wyników

Znaleziono wyników: 1

Liczba wyników na stronie

Wyniki wyszukiwania

Wyszukiwano:
w słowach kluczowych: non-adiabatic effects

Sortuj według:

Ogranicz wyniki do:

Breakdown of the born-oppenheimer approximation in InCl X(1)Sigma(+) electric state

Molski M., Konarski J.

Polish Journal of Chemistry

1998

Vol. 72, nr 7S

1398-1404

Pure rotational transitions of (115)In(35)Cl, (115)In(37)Cl, (113)In(35)Cl and (113)In(37)Cl were analyzed to yield mass-independent radial parameters representing the internuclear potential energy and nonadiabatic rotational effect of the nuclei. From the determined t(In,Cl)-0 parameters, reflecting the purely the nonadiabatic rotational effect, and from experimental value of the dipole moment the rotational g-factor of four isotopic variants of InCl has been evaluated. The quality of the Born-Oppenheimer approximation and the extent of its breakdown in indium monochloride have been examined.