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The effect of thermal treatments on the mechanical and electrical properties of nickel-coated carbon fibre composites

Pierozynski B.

Polish Journal of Chemical Technology

2011

Vol. 13, nr 1

16-19

Nickel-coated carbon fibre (NiCCF) composites may find technological applications within many industrial sectors, including: laptop computers, automotive and military industries. Typically, these applications require that NiCCF be subjected to extensive material processing; thus, optimization of mechanical (and electrical) properties for this material at the stage of its production is of significant importance. The present paper reports the application of specific, high-temperature heat treatments to laboratory-produced 12K50 NiCCF material, carried-out in order to improve the ductility and interfacial adhesion of electrodeposited Ni coating to the surface of carbon fibre substrate.

The effect of cathode deactivation upon hydrogen evolution reaction on nickel-coated carbon fibre

Pierozynski B.

Environmental Biotechnology

2010

Vol. 6, No. 1

1-5

The process of cathodic evolution of hydrogen at metal (or composite) electrodes is one of the most widely studied electrochemical reactions. It has important technological significance in the fields of fuel-cell and battery development. Nickel-coated carbon fibre (NiCCF) offers an attractive, large surface-area catalyst material for the process of cathodic evolution of hydrogen. Such composite materials could potentially be used to produce large area, woven cathodes for the generation of H2 in commercial electrolysers. Kinetics of the hydrogen evolution reaction (HER) at commercially available NiCCF material (Toho-Tenax fibre) were studied in 30 wt.% KOH solution, at room temperature over the cathodic overpotential range: -100 to - 500 mV/RHE. Significance of the cathode deactivation effect (in relation to the corresponding values of the charge-transfer resistance and the cathode potential parameters) upon continuous alkaline water electrolysis has also been discussed.