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1 Polish Journal of Chemistry

1 2005

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Possibility of Some Metals Dissolution in Mixtures of Dimethyl Sulfoxide and Aliphatic Halogen Derivative. Part II. Characteristics of the Metallic Nickel Dissolution Reaction in Binary Organic Mixtures

Lenarcik B., Jurek K.

Polish Journal of Chemistry

2005

Vol. 79 / nr 10

1605-1613

Nickel can be dissolved at temperature 323 K in binary organic mixtures containing dimethyl sulfoxide and one of halogeno aliphatic derivatives: 1,2-dibromoethane or tribromomethane, 1,1,2,2-tetrabromoethane, tetrabromomethane and hexachloroethane. As a result of dissolution of metallic nickel in binary organic system the octahedral nickel(II) complexes were obtained. Products of the dissolution of metallic nickel were characterized by UV-Vis and IR spectroscopy,MS spectrometry, thermal decomposition and analytical methods.