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Al-Sn nanostructured coatings on aluminum surfaces using electrospark alloying and their wear behawior

Yurchenko E. V., Rushika I. D., Agafii V. I., Dikusar A. I.

Journal of Mechanical and Energy Engineering

2018

Vol. 2, No 2

115--120

At electrspark alloying (ESA) of aluminum surfaces using Al-Sn tool-electrode (TE), nanostructuring of manufactured surfaces take place owing to the formation of SnO2 nanofibers. Examining the tribological properties of these surfaces in a friction couple with a counterbody made of hardened steel showed that the wear of counterbody during the friction in the oil and at dry friction exceeds by an order of magnitude and above it the wear of such surfaces.

Nanostructuring of thin Au films by means of short UV laser pulses

Grochowska K., Nedyalkov N., Atanasov P., Śliwiński G.

Opto-Electronics Review

2011

Vol. 19, No. 3

327-332

The particle size distribution, morphology and optical properties of the Au nanoparticle (NP) structures for surface enhanced Raman signal (SERS) application are investigated in dependence on their preparation conditions. The structures are produced from relatively thin Au films (10-20 nm) sputtered on fused silica glass substrate and irradiated with several pulses (6 ns) of laser radiation at 266 nm and at fluencies in the range of 160-412 mJ/cm². The SEM inspection reveals nearly homogeneously distributed, spherical gold particles. Their initial size distribution of the range of 20-60 nm broadens towards larger particle diameters with prolonged irradiation. This is accompanied by an increase in the uncovered surface of the glass substrate and no particle removal is observed. In the absorption profiles of the nanostructures, the broad peak centred at 546 nm is ascribed to resonant absorption of surface plasmons (SPR). The peak position, halfwidth and intensity depend on the shape, size and size distribution of the nanostructured particles in agreement with literature. From peak intensities of the Raman spectra recorded for Rhodamine 6G in the range of 300-1800 cm⁻¹, the relative signal enhancement by factor between 20 and 603 for individual peaks is estimated. The results confirm that the obtained structures can be applied for SERS measurements and sensing.