Alkalides are salts containing alkali metal anions and complexed alkali metal cations. They reduce various organic compounds easily. Alkalides can be also used for the reduction of soluble transition and post transition metal salts in mild homogeneous conditions. Nanoparticles of metals are products of this process. Their further reactions result in nanocrystalline metal oxides, nitrides and carbides as well as electroceramics. This review article presents papers dealing with this subject and shows possible applications of the nanomaterials obtained.
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