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Effect of deposition parameters on kinematics growth and optical properties of PbS nano films deposited by chemical bath deposition

Mousa A. M., Hassen S. M., Mohmoed S.

International Letters of Chemistry, Physics and Astronomy

2014

Vol. 15

1--10

The paper presents a study regarding the kinetic of chemical bath deposition (CBD) PbS nano films. Nano films were deposited from chemical bath containing thiourea, lead nitrite, and ammonia. The deposition kinematics and optical investigations have been performed to compare the properties of the films grown with different precursor solutions. We are able to determine the growth rate as a function of the synthesis conditions and it was found that the growth rate of deposited nano layer affected significantly by synthesis conditions. The main characteristic of nano films is the band gap. This parameter determined from spectroscopy Measurements of transmission, in the energy range of 240-840 nm is influenced by many factors such as deposition time, bath temperature, pH value of the path and molar concentration of the reactants.

Selective infrared absorption and refraction of symmetrical two-layered molecular nanofilms

Rodic D, Skipina B, Pelemis S. S., Jacimovski S. K., Setrajcic J. P.

Optica Applicata

2013

Vol. 43, nr 4

641--649

We have supplemented the already formulated microscopic theory of optical properties of very ultrathin molecular films (quantum nanofilms), i.e., quasi 2D systems parallel to XY planes bounded by two surfaces. The exposure of nanofilms to the external electromagnetic fields has resulted in the creation of excitons, but different than bulk ones in one direction perpendicular to surfaces. The analysis of the dielectric response of the system to perturbation of an external electromagnetic field shows that optical properties of these crystalline nanosystems for low exciton concentration of Frenkel’s excitons strongly depend on boundary parameters and the thickness of the film. In addition, the dynamical absorption and the refraction coefficient show a very narrow and discrete dependence of external electromagnetic field frequency, which is the consequence of both resonance and quantum size effects. Influences of boundary conditions on optical characteristics (through the analyses of dynamical absorption and refraction indices) of these nanostructures were specially and in details explored. The emission and the luminescence spectrum of the whole film have been analyzed and the results compared to experimental data show very good behavior and very good coordination.