Wyniki wyszukiwania - BazTech

1

Fe2+- and Er2+-intercalative modification of porous and electron structure of activated carbon and its influence on supercapacitor parameters

Venhryn B.Ya., Grygorchak I.I., Kulyk Yu.O., Mudry S.I., Strelchuk V V, Budzulyak S I, Dovbeshko G I, Fesenko O M

Materials Science Poland

|

2014

|

Vol. 32, No. 2

272--280

EN

An influence of both porous and electron structure on the processes in an electric double layer (EDL) determining the main working parameters of carbon-based supercapacitors has been studied in order to improve them. The investigations involved impedance spectroscopy, X-ray small angle scattering, confocal micro-Raman spectroscopy, infra-red and M¨ossbauer spectroscopy. Fe2+- and Er2+-intercallative modifications of nanoporous carbon were performed. It was found that the modification process characteristics correlated with the structure parameters of the EDL.

2

Improvement of supercapacitor parameters by nickel ion intercalation into activated carbon

Venhryn B. Y., Grygorchak I. I., Kulyk Y. O., Mudry S. I.

Materials Science Poland

|

2013

|

Vol. 31, No. 1

126-132

EN

The relation between the porous structure and the electron structure in carbon materials was investigated in order to optimize the effiency of the physical-chemical processes in an electric double layer (EDL) formed at the boundary between the carbon material and the electrolyte (KOH 30 % aqueous solution). In particular, an Ni2+ intercalative modification of nanoporous carbon resulted in more than a triple increase in the specific capacitance and a significant improvement of the charge-discharge kinetics in the EDL.

3

Changes in the fractal and electronic structures of activated carbons produced by ultrasonic radiation and the effect on their performance in supercapacitors

Venhryn B., Grygorchak I., Stotsko Z., Kulyk Y., Mudry S., Strelchuk V., Budzulyak S., Dovbeshko G., Fesenko O.

Archives of Materials Science and Engineering

|

2012

|

Vol. 57, nr 1

28-37

EN

Purpose: Effect of ultrasonic irradiation on change of electron structure as well as fractal one of activated carbons and motivation that these changes are most responsible for the improvement of functional parameters in supercapacitors, were the aim of this paper. Design/methodology/approach: Experimental studies were carried out by means of impedance spectroscopy, cyclic voltammetry, X-Ray diffraction, small angle X-Ray diffraction, X-Ray photoelectron spectroscopy, IR-spectroscopy, Micro-Raman spectroscopy and galvanostatic cycling methods. Findings: Ultrasonic modification of carbon is effective method to increase the specific capacitance as well as power of carbon-based supercapacitors. Changes of parameters of double electric layer are tightly related with change of fractal dimension and allow increasing the percolate mobility of charge carries. Research limitations/implications: This research is a complete and accomplished work. Practical implications: Carbon materials, modified by ultrasonic irradiation, can be used as promising electrode materials in energy storage devices of new generation. Originality/value: This work is of urgent importance for studying of physical and chemical processes in energy storage systems. It is shown that method of ultrasonic irradiation is highly effective for modification of carbon-based materials as electrodes in supercapacitors.

4

Metallopolimernye nanokompozity na osnove alifaticeskih poliamidov: polucenie, issledovanie, primenenie

Peseckij S. S., Jurkowski B., Krivoguz Ju. M., Davydov A. A., Bogdanovic S. P.

Zeszyty Naukowe Politechniki Poznańskiej. Budowa Maszyn i Zarządzanie Produkcją

|

2007

|

Nr 4

191-200

EN

A study was conducted of metalopolymeric nanocompositcs prepared by dispersion of metal-containing compounds in molten aliphatic polyamide 6/66 copolymer of s-caprolactam, 50%, and adipic hexamethylene diamine, 50%) with metal-containing compounds (ferric chloride and ferrous oxalate; cupric chloride, cupric formate and cupric acetate; carbonyls of Cr. Mo, W) in an extrusion reactor-mixer can give metalopolymeric nanocomposites. Transition metals create coordination bonds with polyamide macromolecules.