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Application of Statistical Methods for the Comparative Study of the Degree of Pollution of Wastewater Collected from Three Olive Mills in Tangier-Tetouan-Al Hoceima Region (Northern Morocco)

Es Saouini Hind, Bouzid Saida, Trankil Abdellah, Amharref Mina, Bernoussi Abd Samed

Journal of Ecological Engineering

2023

Vol. 24, nr 4

320--332

Olive mill wastewaters represent a severe environmental problem, especially in Mediterranean countries. Indeed, the treatment and recovery processes developed so far remain very limited and their cost is very high. However, treatment by shallow evaporation ponds in the open air remains, until now, the most used technique despite the efforts made. The volume and characteristics of this liquid effluent depend, among other things, on the nature of the extraction process used. In this context, this work aims to evaluate the effect of the mode of trituration and storage in the evaporation ponds on the quality of olive oil mill wastewaters. These effluents were collected from three olive mills located in two different provinces in Northern Morocco during the 2021–2022 olive growing season. The sampling has considered different points according to different steps of the process. The analytical work corresponded to the measurement of in-situ parameters (Temperature (T°), Dissolved Oxygen (DO), Electrical Conductivity (EC) and pH degree (pH)) and other laboratory analysis (Suspension Matter (SM), Dry Matter (DM), Fatty Matter (FM), biochemical (BOD5) and chemical (COD)demands in oxygen). Results showed a high degree of environmental degradation. Indeed, these effluents are characterized, on average, by elevated concentrations of biological and chemical oxygen demands and suspended solids reaching up to 0.43 g/L ± 0.87, 1.69 g/L ±0.71 and 30.78 g/L ±25.1, respectively. This study also showed, except for two-phase olive mill BNANDA, a slightly alkaline nature of the vegetable waters (7.813 m³) is very high considering its equivalence to domestic water. Normalized Principal Component Analysis (ACPN) and Hierarchical Principal Component Classification (HCPC) indicate that differences in the composition of this wastewater were more pronounced between the extraction processes than by the origins of the vegetable waters (fresh or stored in the natural evaporation pond).

Recognition of Main Processes Forming Chemical Composition of the Supraśl River Water

Skorbiłowicz M.

Journal of Ecological Engineering

2016

Vol. 17, nr 1

154--160

The aim of the study was to identify and define the processes that affect the variability of the chemical composition of Supraśl river water at selected measuring points. One of the recognized multivariate statistical methods was used for identification. The research area covered the Suprasl river. Four measuring points were selected on the river – Michałowo, Gródek, Nowodworce, Dzikie. The measuring points were selected in such a way to take into account the impact of the most intense interaction located along the river. Changes in concentration were determined on the basis of monthly analyzes of water samples collected from the Supraśl river in 2003–2012 by the Regional Inspectorate for Environmental Protection (RIEP) in Białystok. The analyses were performed in the RIEP laboratory in Bialystok, which has implemented and maintained a management system that meets the requirements of the norm PN-EN ISO/IEC 17025 + Ap.1:2007 approved by the certificate AB 165. The water samples were subject to determinations of dissolved oxygen concentration, BOD5, CODMn, CODCr, NH3, N-NH4+, NKieldahl, NO3-, N-NO3-, NO2-, N-NO2-, Ntot., PO43-, Ptot and electrical conductivity value. The monthly sum of precipitation was read based on data from the Weather Service “IMGW-PIB Monitor”. The research and analysis results allowed to identify the self-cleaning, nitrification, and de-nitrification processes, as well as enrichment affecting the variability of the chemical composition of the Supraśl river water. The results from the factor analysis showed some prevailing of enrichment processes over internal changes in the aquatic environment of the Supraśl river.