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Interpretation of Vibrational Spectra of Liquid Water

Chumaevskii N., Rodnikova M. N.

Polish Journal of Chemistry

2002

Vol. 76 / nr 9

1363-1370

Based on Raman spectral studies of H2O, D2O, HOD and aqueous solutions of various salts we suggest a new interpretation of vibrational spectra of liquid water. The striking result is obtained that a quite definite set of weak H-bonds corresponds to a quite definite set of the rotational reorientations of the water molecules. The contribution of each orientation depends on the temperature and on the nature of the solved salts.