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Evaluation of transference numbers in mixed conductive lithium vanadate-phosphate glasses

Jozwiak P., Garbarczyk J.E., Wasiucionek M.

Materials Science Poland

2006

Vol. 24, No. 1

148--153

A method for evaluating the transference numbers in mixed electronic-ionic glasses of the Li2O-V2O5-P2O5 system is proposed and tested, basing on the analysis of temperature dependences of the total conductivity of these glasses. The method consists of representing experimental non-Arrhenius temperature dependences of the total conductivity by a sum of two Arrhenius-like contributions. The latter ones were tentatively attributed to the electronic and ionic partial conductivities.