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On the spectral separation of dye mixtures

Pecly José Otávio Goulart, Paiva Carlos Henrique de Paula

Acta Geophysica

2022

Vol. 70, no 5

2423--2435

The fluorescent tracers technique for determining hydraulic and transport parameters in the field and in the laboratory is well established. Common practices include the use of multiple dyes in branches of convergent streams, or the use of multiple dyes to control the quality of the results. However, the quantification of dye mixtures cannot be done correctly by calibration curves constructed from fluorescence intensity peaks. This problem arises because the characteristic wavelengths of the tracers are close, and their fluorescence spectra are wide, which leads to mutual interference in samples containing mixtures of dyes. To assess a spectral separation method, a set of standard solutions containing single tracer and binary mixtures of dyes was prepared and measured using a spectrofluorometer. The fluorescence spectra were processed by software routines written for background subtraction and spectral separation. Pearson Type VII curves fitted well to the fluorescence spectra of the selected dyes and were used to calculate the contribution of each tracer in the mixture by an additive model. The difference between the calculated and the nominal values was smaller after spectral separation and dependent on the concentration ratio of the tracers. Mixtures that had one of the dyes in low concentration could not be detected by the traditional peak method but could be detected and quantified after spectral separation. The support of software routines can lead to higher productivity and improved data quality, and a spectral separation method should be a standard procedure for measuring dye mixtures.

Analysis of the separation methods of optical spectra for individual components

Makhniy V., Kinzerska O., Senko I.

Informatyka, Automatyka, Pomiary w Gospodarce i Ochronie Środowiska

2018

T. 8, nr 4

8--11

A comparative analysis of various methods for the decomposition of broad bands into individual components has been carried out. It is shown that the most universal are the methods of modulation spectroscopy and direct differentiation of conventional spectral characteristics, which, unlike the widely used Alentsev-Fock method, are applicable to spectra of any type (luminescence, transmission, absorption, etc.). The features and capabilities of the direct differentiation method are used to identify the structure in the emission spectra and transmission of ZnSe single-crystal substrates.

Przeprowadzono analizę porównawczą różnych metod dekompozycji szerokich pasm na poszczególne składniki. Pokazano, że najbardziej uniwersalne są metody spektroskopii modulacyjnej i bezpośrednie różnicowanie konwencjonalnych charakterystyk spektralnych, które w przeciwieństwie do powszechnie stosowanej metody Alentseva-Focka mają zastosowanie do widm dowolnego rodzaju (luminescencja, transmisja, absorpcja itp.). Cechy i możliwości bezpośredniej metody różnicowania są stosowane do identyfikacji struktury w widmach emisyjnych i transmisyjnych monokrystalicznych składników ZnSe .