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1
Content available INNUPS. Technologia usuwania i odzysku metali oraz boru ze ścieków z instalacji mokrego odsiarczania spalin
Nowa Energia
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2022
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nr 3
12--15
PL
PGE Energia Ciepła zmodernizowała w Elektrociepłowni Gdyńskiej układ odsiarczania ścieków z mokrego odsiarczania spalin, rozbudowując go o innowacyjne rozwiązanie, jakim jest instalacja wykonana w technologii INNUPS. Wdrożenie to jest odpowiedzią na potrzebę poszukiwania nowych, niezawodnych i dużo sprawniejszych metod oczyszczania ścieków pochodzących z mokrego odsiarczania spalin.
2
Content available Selective solvent extraction of some heavy metal ions from aqueous solutions by octafunctionalized resorcin[4]arenes
Kończyk Joanna, Dlugosz Jan
Physicochemical Problems of Mineral Processing
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2020
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Vol. 56, iss. 2
271--285
EN
This paper presents the results of the study on the extraction capacity of 1,8,15,22-tetra(1- heptyl)resorcin[4]arene and its octasubstituted derivatives containing thiophosphoryl, ester and amide groups in the presence of Pb(II), Zn(II), Cd(II) and Cr(III) in solvent extraction process. Effects of the structure and concentration of the resorcinarene extractant and the composition of the aqueous phase as well as its acidity on the efficiency and selectivity of removal of the examined metal ions from model aqueous solutions were determined. The 1:1 stoichiometry for complexes formed between Pb(II) and Cr(III) and the octasubstituted resorcin[4]arenes was determined by classical slope analysis and loading test.
3
Content available Solvent extraction of copper(II) from chloride solutions using 1,1′-dialkyl-2,2′ bibenzimidazoles as extractants
Mądrzak-Litwa Iwona, Borowiak-Resterna Aleksandra
Physicochemical Problems of Mineral Processing
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2019
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Vol. 55, iss. 5
1165--1178
EN
The solvent extraction ability of 1,1′-dialkyl-2,2′-bibenzimidazoles (L) for the recovery of copper(II) ions from aqueous chloride solutions has been investigated. It was found that 1,1′-didecyl- 2,2′-bibenzimidazole is a useful extractant for the separation of copper(II) ions from both weakly and strongly acidic solutions. Copper(II) can be effectively stripped of organic solutions by a water or ammonia solution in a one-stage process. In low acidity media (pH feed > 1), the extraction percentage of Cu(II) increases with an increase in metal ions and chloride concentrations. Copper(II) ions are extracted as binuclear complexes (CuCl2) 2L2 (L = extractant). The constructed McCabe−Thiele diagram shows that the reduction of copper(II) ions concentration from 25 to approximately 5 g/dm3 in an aqueous feed is possible in two extraction stages. When [HCl] feed ≥ 1 M, (LH+)2(CuCl 4 2)L complex is formed. From the strongly acidic solutions ([HCl] = [LiCl] = 4 M), almost 100% of copper(II) ions can be removed by 1,1′-didecyl-2,2′-bibenzimidazole. Benzyl alcohol, used as an organic phase modifier, enables the selective extraction of copper(II) over zinc(II) ions from a weakly acidic chloride solution.
4
Content available Surfactant assisted removal of Cu(II), Cd(II) and Pb(II) from contaminated soils
Ramamurthy A., Schalchian H.
Environment Protection Engineering
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2013
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Vol. 39, nr 3
87--99
EN
The study deals with the removal of residual contaminants Cu(II), Cd(II) and Pb(II) from soil using surfactants sodium dodecyl sulfate (SDS), sodium dioctyl sulfosuccinate, and Triton x-100. Surfactants were used with and without chelating agent ethylenediaminetetraacetic acid (EDTA). SDS (10 mM) was the most effective surfactant for removing metals. Replacing distilled water with SDS enhanced metal removal by the factor of 5.5, 28.8, and 29.1 for Cu(II), Cd(II), and Pb(II), respectively. SDS with EDTA was efficient in removing metals. Interaction of metal ions with respect to adsorption and desorption were also studied.
5
Content available remote Precipitation of heavy metals from industrial wastewater by Desulfovibrio desulfuricans
Kosińska K., Miśkiewicz T.
Environment Protection Engineering
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2012
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Vol. 38, nr 2
51--60
EN
Wastewater from leather tanning, electroplating, organic dye production and non-ferrous metallurgy was treated in a batch anaerobic bioreactor of the total volume of 2.7 dm3 using Desulfovibrio desulfuricans for the removal of Crtotal, Cu(II), Fe(II), Ni(II) and Zn(II) as metal sulfides. Except the tannery effluent, the wastewater samples were supplemented with an appropriate quantity of swine manure in order to enrich them with simple organic compounds and biogenic elements (N and P), and thus upgrade the sulfate reducing activity of D. desulfuricans. The metal removal efficiencies obtained varied from 85.2% to 98.96%.
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