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1 Polish Journal of Chemistry

1 1998

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The CuGaSe2-HgSe and CuInSe2-HgSe systems

Olekseyuk I.D., Parasyuk O.V., Galka V.O.

Polish Journal of Chemistry

1998

Vol. 72, nr 1

49-54

Phase diagrams in the CuGaSe2-HgSe and CuInSe2-HgSe systems have been constructed using differential thermal, X-ray phase and microstructural analyses. The CuGaSe2-HgSe system is of the peritectic type. Solid solution of the constituent components have been found and their limit compositions have been established. They contain 0-3 ans 63-100 mol. % HgSe at 870 K. The CuInSe2-HgSe system is of the first type, due to Roozeboom classification. A continuous range of solid solutions exists between HgSe and the high-temperature beta-modification of CuInSe2. The solid solution are created on the basis of alpha-CuInSe2 which contains up to 7 mol. % HgSe at 870 K.