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Ograniczanie emisji rtęci ze spalania węgla w kotłach fluidalnych za pomocą modyfikowanych sorbentów sodowych

Łuczkowska D., Walawska B.

Przemysł Chemiczny

2015

T. 94, nr 7

1196-1199

Badano proces ograniczenia emisji rtęci ze spalania węgla kamiennego w kotłach fluidalnych przy zastosowaniu surowego bikarbonatu sodu, sody oczyszczonej oraz aktywowanych mechanicznie i chemicznie sorbentów sodowych. Wybrane sorbenty wprowadzano w odpowiednich proporcjach Na/S = 0,75 i 3 do przewodu spalinowego, gdzie panowała temp. ok. 300°C. Wyniki badań potwierdziły skuteczność stosowania modyfikowanych sorbentów sodowych w procesie usuwania rtęci ze spalin.

Raw and pure NaHCO₃ were modified mech. by milling or chem. by adding Na₂CO₃·1.5H₂O₂ (10% by mass), CaO₂ (10% by mass) or urea (0.5% by mass) and introduced into the exhaust gas channel. The fired coal contained S 1.28% and Hg 120.1 ng/g. The mercury contents in the fuel and sorbent, and mercury mass emitted to the atm. for the processes conducted with and without use of the sorbent were detd. The assays were performed for Na/S mass ratios 0.75 or 3. The best efficiency of the Hg removal from flue gases was achieved for the mech. modified raw NaHCO₃ and pure NaHCO₃ (61% and 70%, resp.) both for the Na/S mass ratio 3.

Coal Cleaning Versus the Reduction of Mercury and other Trace Elements’ Emissions from Coal Combustion Processes

Zajusz-Zubek E., Konieczyński J.

Archives of Environmental Protection

2014

Vol. 40, no. 1

115--127

Samples of steam coal used in heat and power plants as well as densimetric fractions obtained on a laboratory scale by dense organic liquid separation have been examined. The contents of ash, mercury, chromium, cadmium, copper, nickel and lead have been determined in coal, in the light and medium fraction as well as in the refuse. The degree of removal of mineral matter and the examined heavy metals as well as the coal combustible parts yield have been determined. Examination of 5 coals revealed that it is possible to remove 41% of mercury and more than 35% of other heavy metals bound to mineral matter in coal.