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1 Kaim S.

1 2013

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Analitical criteria of homogeneous and heterogeneous detonation of liquid energetic materials

Kaim S.

Materiały Wysokoenergetyczne

2013

T. 5

5--13

Statistical theory of liquids is used to investigate mechanism of detonation initiation on fronts of flat shock waves in homogeneous liquid and in liquid containing spherical nanopores. We calculated thermodynamic parameters of liquid methane sufficient for shock dissociation of molecules at a front of a shock wave. Calculations of the average single-particle force potential show that at high pressures and temperatures atoms and molecules get emitted from the surface into a nanopore with hyper-thermal speeds. Implosion of spherically symmetric stream of molecules may lead to destruction of the molecules at impact. We explained existence of top and bottom bounds for pressure during detonation initiation in heterogeneous energetic materials. In terms of pair interaction potentials and correlation functions there are formulated criteria for boundary values of thermodynamic parameters which are required for initiation of homogeneous and heterogeneous detonations based on the "hot spot"’ mechanism.