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The Silver(I) – Complexes of Cyclic Polyamines with Pendant-arm Modification

Wyrwa J., Kira J., Pankiewicz R., Schroeder G.

Polish Journal of Chemistry

2006

Vol. 80, nr 10

1633-1644

The complex formation for two different groups of cyclic polyamines with four or six nitrogen atoms and with pendant-arm modification and silver(I) ions in propylene carbonate has been studied by electron spray ionization mass spectrometry (ESI MS), potentiometric and Austin Model 1 (AM1d) semiempirical methods. The stability constants of complexes are determined by potentiometric method. The structure of those complexes are visualised by AM1d semiempirical calculations.