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Studies on the Complexation of Alkali Metal Cations by Macrocyclic Diamides Using Electrospray Ionization Mass Spectrometry (ESI-MS)

Tarnowski P., Danikiewicz W., Jurczak J.

Polish Journal of Chemistry

2004

Vol. 78 / nr 7

927-935

Several macrocyclic diamides have been tested as ligands for complexation of alkali metal cations. Electrospray ionization mass spectrometry was found to be a perfect tool for investigation of host-guest interaction between ligands and cations studied. Effect of the ring size and regioisomerism of the amido groups on complexation properties of ligands were also investigated.