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Influence of the air-entraining agent in the concrete coating on the reinforcement corrosion process in case of simultaneous action of chlorides and frost

Raczkiewicz W.

Advances in Materials Science

2018

Vol. 18, nr 1(55)

13--19

The paper presents the test results to evaluate the effect of air-entraining agent addition on the intensity of reinforcement corrosion in concrete with blast-furnace slag cement in the case of simultaneous action of chloride corrosion and frost. Two groups of reinforced concrete specimens were prepared for the study. The first group of specimens included air-entraining agent addition and the other group was prepared without air-entraining agent. The blast-furnace slag cement (CEM III/A) was used for the specimens. Two parallel reinforcing rods were placed in each specimen. The specimens were subjected to 120 cycles of freezing and thawing in 3% NaCl solution to induce corrosion on the reinforcement. To determine the occurrence of the reinforcement corrosion and estimate the corrosion activity the non-destructive electrochemical galvanostatic pulse method was used. On each specimen the corrosion current density of the reinforcement was measured as well as the reinforcement stationary potential and the concrete coating resistivity, i.e. values indicating the ongoing reinforcement corrosion. Measurements were made on all specimens in two steps: before freezing and thawing cycles in 3% NaCl solution and after the cycles. The analysis of the obtained results allowed to determine differences in corrosion processes intensity on the reinforced bars in the concrete specimens depending on whether or not the air-entraining agent was added. Based on the analysis it was found that in the case of simultaneous action of chloride corrosion and frost it is advisable to use both blast-furnace slag cement and air-entraining agent. The use of only blast-furnace slag cement (although it is a chloride resistant cement), without the addition of air-entraining agent is insufficient.

Inverse methods in corrosion research and materials degradation

Filipek R., Szyszkiewicz-Warzecha K.

Ochrona przed Korozją

2017

nr 11

358--363

Applications of inverse methods in corrosion research and materials degradation are demonstrated. Two examples concern corrosion of reinforcement in concrete structures and one concerns a blast furnace. In the first example, a diffusion model and diffusion with reactions model are used to determine a chloride diffusion coefficient in concrete which can be applied to predict the lifetime of a building construction. In the second example, determination of corrosion state based on solution of inverse problems defined for transient response (galvanostatic pulse method) is shown. Finally, it is demonstrated how the inverse problem of the heat transport can be used to estimate degradation of refractory material being in contact with molten metal based on temperature readings in selected locations of the blast furnace.

Przedstawiono zastosowania metody odwrotnej w badaniach nad korozją i degradacją materiałów. Dwa przykłady dotyczą korozji zbrojenia stalowego w konstrukcjach żelbetowych, a jeden dotyczy wielkiego pieca. W pierwszym przykładzie, model dyfuzyjny oraz dyfuzyjno- reakcyjny zostały użyte do wyznaczenia współczynnika dyfuzji chlorków betonie, który następnie może być wykorzystany w celu oszacowania czasu użytkowania konstrukcji budowlanej. W drugim przykładzie oszacowanie stanu procesu korozyjnego dokonano na podstawie rozwiązania problem odwrotnego zdefiniowanego dla czasowej odpowiedzi potencjałowej (metoda impulsu galwanostatycznego). Ostatni przykład demonstruje jak metoda odwrotna może być wykorzystana do problemu transport ciepła w celu oceny degradacji wyłożenia ogniotrwałego będącego w kontakcie ze stopionym metalem w oparciu o odczyty temperatury wielkiego pieca w wybranych punktach.