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Nitriding of car engine parts using ZeroFlow method

Kowalska J., Małdziński L.

Combustion Engines

2016

R. 55, nr 4

3--7

This article presents new method of controlled gas nitriding called ZeroFlow, which is used for nitriding of selected car engine parts. Parts such as crankshafts, camshafts, piston rings, poppet valve springs and discs, piston pins or nozzles for unit injectors was nitrided with ZeroFlow method so far. Through the use of simulation models it was possible to develop the specially dedicated process with specific parameters for each of this parts; it allows forming of nitride layer with strictly expected properties: required phase structure with thicknesses of each zone occurs in it and required hardness distribution. Moreover, through the use of simulation models this layers were obtained in in the shortest possible time, which is connected with the lowest energy consumption; therefore, nitriding process using ZeroFlow method is both economical and environmentally friendly. This article will discuss the essence of controlled gas nitriding process, with an emphasis on the influence of process parameters on results of nitriding process. This information are the basis to understand the issue of the kinetics of nitrided layer growth, and as it follows – for its practical application in designing, regulation and control of nitriding processes using simulation models (simulator of the kinetics of nitrided layer growth). Designing of ZeroFlow nitriding processes on the basis of the kinetics of nitrided layer will be shown on the example of nitriding of crankshafts for sports car engines.

Nitrogen Availability Of Nitriding Atmosphere In Controlled Gas Nitriding Processes

Michalski J., Burdyński K., Wach P., Łataś Z.

Archives of Metallurgy and Materials

2015

Vol. 60, iss. 2A

747--754

Parameters which characterize the nitriding atmosphere in the gas nitriding process of steel are: the nitriding potential KN, ammonia dissociation rate α and nitrogen availability mN2. The article discusses the possibilities of utilization of the nitriding atmosphere’s nitrogen availability in the design of gas nitriding processes of alloyed steels in atmospheres derived from raw ammonia, raw ammonia diluted with pre-dissociated ammonia, with nitrogen, as well as with both nitrogen and pre-dissociated ammonia. The nitriding processes were accomplished in four series. The parameters selected in the particular processes were: process temperature (T), time (t), value of nitriding potential (KN), corresponding to known dissociation rate of the ammonia which dissociates during the nitriding process (α). Variable parameters were: nitrogen availability (mN2), composition of the ingoing atmosphere and flow rate of the ingoing atmosphere (FIn).

Parametrami charakteryzującymi atmosferę azotującą w procesie azotowania gazowego stali są: potencjał azotowy KN, stopień dysocjacji amoniaku α oraz rozporządzalność azotu mN2. W artykule omówiono możliwości wykorzystania rozporządzalności azotu atmosfery azotującej w projektowaniu procesów azotowania gazowego stali stopowych w atmosferach azotujących uzyskanych z amoniaku, z amoniaku rozcieńczonego zdysocjowanym amoniakiem, azotem oraz azotem i zdysocjowanym amoniakiem. Procesy azotowania wykonano w czterech seriach. Parametrami ustalonymi w poszczególnych seriach była temperatura procesu (T), czas (t), wartość potencjału azotowego (KN), któremu odpowiada określona wartość stopnia dysocjacji amoniaku zdysocjowanego podczas procesu azotowania (α). Parametrami zmiennymi była rozporządzalność azotu (mN2), skład atmosfery wlotowej i natężenie przepływu atmosfery azotującej wlotowej (Fw).