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EN
This research focused on hydrocarbon removal from contaminated soil, using co-composting methods on a laboratory scale. The soil samples were taken from ship demolition sites in Tanjung Jati, Bangkalan Regency, Madura Island. Therefore, this study aimed to investigate the efficiency of bioremediation process using the co-composting method for hydrocarbon removal. The co-composting was treated under aerobic conditions, and manual stirring for aeration was performed every 2 days. Moreover, the values of hydrocarbon and total bacterial population levels were measured on day 0, 30, and 60. The results of the study at location 1 showed that for 60 days, the cocomposting of contaminated soil in the control reactor was 33.36%, kitchen waste (34.99%), local cattle rumen waste (59.41%), and soil mixed kitchen and cattle rumen waste (61.01%). Meanwhile, at location 2, they were 28.50%, 64.18%, 42.67%, and 67.03% respectively. The largest total bacterial population was in the nutrient agar media with stratification of up to 10-8.
PL
W artykule przedstawiono uwarunkowania prawne i technologiczne procesów przekształcania odpadów kuchennych w wartościowy produkt (fermentat lub kompost) do rolniczego wykorzystania. Odpady kuchenne mogą być przekształcane biologicznie w procesach recyklingu organicznego (R3) poprzez kompostowanie czy fermentację metanową. Z uwagi na wysoką zawartość frakcji organicznej, odpady kuchenne uznawane są za pożądany ko-substytut do współfermentacji z osadami ściekowymi. W artykule przedstawiono analizę formalno-prawną oraz wytyczne technologiczne dla prowadzenia procesu współfermentacji osadów ściekowych i odpadów kuchennych. Kontrolowanie prowadzenia procesu współfermentacji pozwala na spełnienie kryterium jakościowego produktu finalnego (poferment) i umożliwia jego późniejsze zastosowanie rolnicze.
EN
The aim of this study was to investigate the effect of pH on the dark fermentation process of kitchen waste by specifying the composition of the volatile fatty acids (VFA), H2 and by drawing the carbon balance. Studies were carried out in 8 dm3 batch bioreactor in mesophilic conditions. The kitchen waste from the city of Lodz were used as a substrate. Based on the study, it was observed that most of the VFA was produced during the first two days of the process, while in the following days the production was diminished. The highest production of VFA (19.5 g/dm3) was obtained in the bioreactor, where the pH was 7 and 8. Analyzing the produced VFA it was observed that mostly the acetic and butyric acid had been produced. Most of acetic acid (over 70 %) was obtained in fermenter with pH 7 and 8. In contrast, most of the butyric acid (over 40 %) was in the bioreactor with a pH of 6. Production of H2 was in the range from 4.29 to 26.5 dm3, wherein the largest amount of H2 was created in the bioreactor with a pH of 6.
EN
Purpose: This study focuses on increasing production of biogas as an alternative energy from biodegradable wastes (BWs) using BSA coated iron oxides nanoparticles, in view of solving waste management at household level. Many attempts have been performed in order to increase biogas production, including thermal pre-treatment of organic waste, but all of them present limited industrial applications. Iron has been shown to enhance anaerobic digestion, but there are severe drawbacks for introducing the metal ion in an anaerobic closed reactor. Design/methodology/approach: Process for the production of biogas from biodegradable material which comprises the steps of: (a) adding the biodegradable material to the Bio- reactor,(b) inoculating the microorganisms in the digester,(c) synthesis iron oxides and BSA powder coated on the particles (d) adding a colloidal solution of surface-modified BSA-iron oxide nanoparticles to the reactor; (e) providing anaerobic conditions; (f) carrying out the anaerobic digestion; and (g) collecting the biogas, wherein the steps (a), (b) and (c) can be carried out in any order. It also comprises the use of BSA-iron oxide nanoparticles capable of supplying Fe ions to the media for biogas production in anaerobic conditions and in the presence of Fe ions in the media.
EN
This study determined the possibility of using the vermicompost produced from kitchen waste (by Eisenia fetida earthworms) to grow sugar peas. Its influence on the dynamics of sprouting of peas and their growth to 21st day was investigated in a pot experiment. Four combinations were realised (control – standard garden soil; (50W) – its mixture with 50% of vermicompost; (25W) and (10W) – with 25% and 10% of vermicompost addition respectively (n=5)). Vermicompost from kitchen waste turned out to be useful in the cultivation of peas. No significant differences in the impact of all the analysed substrates on the sprouting of this plant were found. A 10% vermicompost addition (10W) was shown to be the most favourable substrate. Its positive influence was shown in the impact on the increase of total average mass (by 33%; p<0.001) and height of the plants (by 12%; p<0.05) and average mass (by 39%; p<0.001) and length (by 12%; p<0.05) of stems.
PL
O prawidłowym przebiegu fermentacji decydują: rodzaj substratu, obecność odpowiednich populacji mikroorganizmów oraz parametry środowiskowe, wpływające na ich aktywność i szybkość przemian. W literaturze obszernie opisano wpływ na efektywność procesu fermentacji parametrów takich, jak: pH, temperatura, obciążenie komór ładunkiem organicznym i czas fermentacji oraz stężenia składników pokarmowych i związków toksycznych zarówno dla procesów "mokrych" i "suchych", jak i przebiegających w układach jedno- lub w dwustopniowych, w sposób ciągły lub okresowy [1, 2, 4÷7]. Informacje o wpływie na przebieg fermentacji wymiarów cząsteczek odpadów są dotychczas nieliczne i stosunkowo skąpe. Wiadomo jedynie, że zmniejszenie rozmiarów cząstek i wynikające stąd zwiększenie ich powierzchni właściwej powoduje wzrost szybkości hydrolizy, pierwszego etapu fermentacji odpadów organicznych [3]. Efektem jest zwiększenie produkcji gazu, zwłaszcza w przypadku fermentacji substratów o wysokiej zawartości materiałów o niskiej podatności na rozkład biologiczny. Według Palmowskiego i Müllera [8] w przypadku małych cząstek, o powierzchni właściwej większej niż 20 m2/kg wpływ ten jest niewielki, rośnie natomiast gwałtownie przy rozdrabnianiu cząstek dużych, o powierzchni właściwej od 3 do 20 m2/kg. Wzrost szybkości produkcji gazu prowadzi do skrócenia czasu fermentacji, co stwarza możliwość zmniejszenia wielkości komory bez strat w produkcji gazu. Negatywnym efektem rozdrobnienia cząstek jest wzrost oporu właściwego przefermentowanych odpadów. W artykule przedstawiono wpływ stopnia rozdrobnienia makulatury i odpadów kuchennych na wydajność procesu fermentacji metanowej prowadzonej w mezo- i termofilowym zakresie temperatury. Odpady objęte badaniami są głównymi ulegającymi biodegradacji składnikami odpadów komunalnych, o różnej podatności na biologiczny rozkład. Według Imhoffa [4] jednostkowa produkcja biogazu (JPB) z makulatury w procesach mezofilowych wynosi 220 dm3/kg sm (260 m3/kg smo) przy zawartości metanu 63% (v/v). JPB z odpadów kuchennych (pozostałości owoców i warzyw) wynosi od 350 do 500 dm3/kg smo przy zawartości metanu w gazie 60÷75% [ub od 400 do 700 dm3/kg smo przy zawartości metanu 58-65 %.
EN
The hydrolysis of polymers which are difficult to decompose, such as cellulose, lignin, and even decomposable fats, proteins and carbohydrates, is generally considered as a step limiting the fermentation of solid wastes. Reduction of size of molecules and increasing specific surface area available for microbial may improve the speed and efficiency of gas production during the fermentation. The article presents the effects of granulation of paper and kitchen waste for efficiency of methane fermentation in thermophilic and mesophilic environment. The study was performed in a laboratory scale. Wastes were divided into five different grain sizes. During the mesophilic fermentation of paper the highest biogas production unit (JPB) was obtained for samples with a maximum reduction of grain size P-2 (538 dm?/kg VS), and lowest for the largest sample size P-6 (337 dm?/kg VS). Unit production of methane (JPM) ranged from 231 dm?/kg VS (P-2) to 144 dm?/kg VS (P-5). During thermophilic fermentation, JPB also achieved the highest value for the sample P-2 (592 dm?/kg VS), and lowest for P-6 (367 dm?/kg VS). JPM ranged from 273 dm?/kg VS (P-2) to 149 dm?/kg VS (P-6). Mesophilic fermentation of kitchen waste with the smallest grain size showed maximum JPB amounted to 808 dm?/kg VS, during the thermophilic fermentation of 791 dm?/kg VS (Fig. 5). With the increasing grain size of samples JPB decreased to 757 dm?/kg VS (P-6) in mesophilic fermentation and to 768 dm?/kg VS (P-3) and 771 dm?/kg VS (P-6). JPM from maximum fragmentated samples (P-2) was 330 dm?/kg VS during the mesophilic fermentation and 375 dm?/kg VS during thermophilic fermentation. It decreased with increasing grain size of waste up to 273 dm?/kg VS (P-5) during the mesophilic fermentation and to 337 dm?/kg VS (P-6) in thermophilic process. JPB of paper during mesophilic fermentation was from 1.2 (P-5 and P-6) to 1.9 (P-2) times higher than the value given by Imhoff in relation to dry matter and respectively from 1.3 to 2.1 times higher in relation to the dry organic matter [4]. Unfortunately received gas was much poorer in methane production. JPB of paper accounted from 80% (P-5) to 130% (P-2) values specified by Imhoff in relation to dry matter and 90% (P-5) to 140% (P-2) values referred to the dry organic matter. For paper both JPB and JPM increased linearly with the decrease of grain replacement diameter in experiments conducted in mesphilic and thermophilic range of temperatures. The coefficients of determination for most relationships were very high. For paper ranged from 0.93 to 1.00, and for kitchen waste from 0.66 to 0.98. Fermentation of kitchen waste shoved that impact of fragmentation on the JPB and JPM was negligible compared to the paper. The studies confirm the positive effect of fragmentation of organic solid waste which are hardly decomposable (paper) for their biodegradability under anaerobic conditions. Biogas production increased almost linearly with decreasing replacement grain diameter for both types of fermentation. Methane fermentation of difficult degradable waste (paper) their fragmentation is reasonable but it's showed no practical importance for the easily biodegradable waste. Fragmentation of wastes hardly biodegradable provides greater amounts of produced biogas and obtain a smaller mass of solid waste after fermentation.
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