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EN
Hydrogen is the fuel of the future, therefore many hydrogen production methods are developed. At present, fuel cells are of great interest due to their energy efficiency and environmental benefits. A brief review of effective formation methods of hydrogen was conducted. It seems that hydrogen from steam reforming of methanol process is the best fuel source to be applied in fuel cells. In this process Cu-based complex catalysts proved to be the best. In presented work kinetic equations from available literature and catalysts are reported. However, hydrogen produced even in the presence of the most selective catalysts in this process is not pure enough for fuel cells and should be purified from CO. Currently, catalysts for hydrogen production are not sufficiently active in oxidation of carbon monoxide. A simple and effective method to lower CO level and obtain clean H2 is the preferential oxidation of monoxide carbon (CO-PROX). Over new CO-PROX catalysts the level of carbon monoxide can be lowered to a sufficient level of 10 ppm.
PL
Przeprowadzono badania zastosowania katalizatorów miedziowych do produkcji wodoru w procesie rozkładu metanolu. Badano katalizatory w postaci tlenków metali CuOZnOZrO2 z dodatkami tlenku galu, chromu oraz chromu i ceru, a także katalizator CuOZnOAl2O3 promowany tlenkiem cyrkonu. Najwyższą wydajność wodoru wykazują katalizatory: CuOZnOAl2O3 promowany tlenkiem cyrkonu oraz katalizator CuOZnOZrO2 z dodatkiem tlenku galu. Stwierdzono, iż katalizator wytworzony metodą hydrotalkitową wykazuje najlepszą aktywność w badanym procesie.
EN
The studies of Cu catalyst usage in a hydrogen production in the methanol decomposition process were performed. Oxide metal of CuOZnOZrO2-based catalysts with Ga, Cr and Ce additives and CuOZnOAl2O3-based ones promoted by Zr were investigated. The highest hydrogen yield was achieved with CuOZnOAl2O3ZrO2 catalysts and CuOZnOZrO2Ga2O3 ones. It was established that the catalyst produced by hydrotalcite method showed the best activity.
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