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1 Polish Journal of Chemistry

1 2004

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Application of Isotachophoresis for Determination of Anionic Forms of Phosphonic Acids

Górecki H., Szczygieł B, Drela I.

Polish Journal of Chemistry

2004

Vol. 78 / nr 9

1691-1702

Using a capillary electrophoresis analyser, the concentrations of anionic forms of 2-phosphonobutane-1,2,4-tricarboxylic acid (PBTC) and N-trismethylenephosphonic acid (NTMP) were determined by the isotachophoresis method. The measurements were performed at pH = 4.2, 6.0 and 8.0. In each case the proper leading/terminating electrolyte system was selected on the basis of literature and authors'own research. The results of isotachophoretic analyses were found to be in good agreement with the results derived from dissociation constants determined by potentiometric method. Considerable difficulties were encountered in interpretation of the results obtained for pH = 8.0 since individual steps in the isotachopherograms were fuzzy and distorted probably due to incomplete separation of the analysed sample into zones. Knowledge of the kind and concentration of ligand forms of chelating compounds, to which PBTC and NTMP belong, can be useful for reclamation of soils polluted with heavy metals.