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EN
The present study investigates the effects and mechanisms of aluminum (Al(III)) and iron (Fe(III)) ions on the flotation efficiency of potassium feldspar (K-feldspar) within oleate collector systems. The study employs micro-flotation experiments, solution chemistry calculations, zeta potential measurements, and FT-IR and XPS analyses to demonstrate that Al(III) and Fe(III) ions can significantly improve the flotation recovery of K-feldspar by altering its surface charge, bonding properties, and adsorption modes. The study also develops adsorption models for the flotation of K-feldspar activated by Al(III) and Fe(III), revealing the synergistic impacts of metal ion hydrolysis products and sodium oleate in the formation of hydrophobic complexes.
EN
Among all known inorganic pollutants of wastewater and natural water that adversely affect water bodies, different living organisms and human beings, iron compounds are the most common. Before discharging the wastewater into water bodies, it is important to remove iron ions from wastewater. The application of capillary materials in water and wastewater treatment is a promising direction of ecology and technology. The capillary properties of materials allow the development of quite simple, autonomous, highly efficient and energy-saving systems for water purification. The aim of the present paper was the investigation of the influence of the basic conditions of the filtration process with the application of capillary materia on the efficiency of iron ions removal. The initial concentration of the model solution, pH and temperature of the filtration process, as well as the contact area of the liquid phase with oxygen of the air were studied. The proposed method is appropriate for the treatment of water in the concentration range from 5 to 10 mg/dm3 with an optimum pH in the range of 4–7. The experimental data showed high efficiency of capillary materials application, providing sufficient removal of iron ions from low concentrated solutions, compared to the traditional method of precipitation. The main advantage of the capillary materials is the simplicity of their application, quite high degree of purification and there no need to consume electricity or additional reagents, which allows creating autonomous water treatment facilities and plants.
3
Content available remote Zastosowanie złóż chemicznie aktywnych do odżelaziania i odmanganiania wody
PL
W artykule przedstawiono charakterystykę wybranych mas katalitycznych, dostępnych obecnie na polskim rynku. Materiały te służą do wysoko efektywnego usuwania związków żelaza i manganu z wody. Na złożach filtracyjnych (z testowanych mas) przeprowadzono badania laboratoryjne, które miały określić ich skuteczność w uzdatnianiu wód wgłębnych. Stwierdzono, że różnice wynikające z budowy i właściwości mas sprawiają, że każda z nich powinna być dokładnie dostosowana do jakości wody, zastosowanej technologii uzdatniania oraz warunków eksploatacyjnych. Wybór masy katalitycznej dla określonej SUW powinien być każdorazowo poprzedzony badaniami technologicznymi w skali laboratoryjnej. Z testowanych złóż filtracyjnych najbardziej uniwersalnym i efektywnym okazał się "zielony piasek" (masa MZ-10), naturalny zeolit pokryty dwutlenkiem manganu.
EN
The paper presents characteristics of selected catalytic masses available presently on Polish market. Such materials serve for highly-effective removal of iron and manganese compounds from water. A number of laboratory tests were carried out on filtration beds (of tested materials) in order to determine their effectiveness in underground water treatment. It was found that differences, resulting from the material structure and properties, lead to conclusion that each filtration bed should be precisely adjusted to the quality of water to be filtered, as well as to the applied watertreatment process and process-running conditions. Prior to any selection of catalytic mass for a specific water-treatment station, the process should first be tested in laboratory scale. Natural zeolite covered with manganese dioxide, also called a "green sand" and sold here as the MZ-10 mass, proved to be most universal and effective material from the filtration beds tested.
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