Wyniki wyszukiwania - BazTech

Ograniczanie wyników

2 Polish Journal of Chemistry

Znaleziono wyników: 2

Liczba wyników na stronie

Wyniki wyszukiwania

Wyszukiwano:
w słowach kluczowych: iron(III)-iron(III)

Sortuj według:

Ogranicz wyniki do:

Synthesis and magnetic Studies of mi-Iodanilato-Bridged Iron(III)-Iron(III) Binuclear Complexes

Li Y., Yan C. -W., Guan H. -S.

Polish Journal of Chemistry

2003

Vol. 77 / nr 8

935-942

Four new _-iodanilato-bridged binuclear iron(III) complexes have been prepared and identified: [Fe2(IA)L4](ClO4)4, where IA represents the dianion of iodanilic acid and L denotes 2,2_-bipyridine (bpy); 1,10-phenanthroline (phen), 5-chloro-1,10-phenanthroline (Cl-phen) or 5-nitro-1,10-phenanthroline (NO2-phen). Based on elemental analyses, molar conductivity, magnetic moment of room-temperature measurements, IR and electronic spectra studies, these complexes are proposed to have extended IA-bridged structures consisting of two iron(III) ions, each in a distorted octahedral environment. The complexes [Fe2(IA)(bpy)4](ClO4)4 (1) and [Fe2(IA)(phen)4](ClO4)4 (2) were further characterized by variable temperature (4.2~300 K) magnetic susceptibility measurements and the observed data were successfully simulated by the equation based on the spin Hamiltonian operator,_ _ _ H = 2JS S 1 2 Ĺ , giving the exchange parameter J = -6.9 cm-1 for (1) and J = -9.8 cm-1 for (2). These results are commensurate with antiferromagnetic spin-exchange interaction between the two iron(III) ions within each molecule. The influence of halogen substituents in the bridging ligand on magnetic interactions between the metal ions of this kind of complexes is also discussed.

Synthesis, Characterization and Magnetic Analysis of Bromanilato-Bridged Binuclear Iron(II) Complexes

Li Y., Zeng X.

Polish Journal of Chemistry

2000

Vol. 74, nr 2

173-180

Five new bromanilato-bridged binuclear iron(III) complexes have been synthesized and characterized, namely [fe(BA)L4](ClO4)4 where BA represents the dianion of bromanilic acid and L denotes 2,2'-bipyrydine (bpy); 1;10-phenanthroline (phen), 5-chloro-1,10-phenanthroline (Cl-phen), 5-bromo-1,10-phenanthroline (Br-phen) or 5-nitro-1,10-phenanthroline (NO2-phen). Based on elemental analyses, molar conductivity, magnetic moment of room-temperature measurements, IR and electronic spectra studies, these complexes are proposed to have extended BA-bridged structures consisting of two iron(III) ions, each in a distorted octahedral environment. The complexes [Fe2(BA)(bpy)4](ClO4)4 (1) and [Fe2(BA)(phen)4](ClO4)4 (2) were further characterized by variable temperature (4.2-300 K) magnetic susceptibility measurements and the observed data were successfully simulated by the equation based on the spin Hamiltonian operator, H=-2jS1*S2, giving the exchange parameter J=-3.6 cm-1 for (1) and J=-7.9 cm-1 for (2). These results are comensurate with weak antiferromagnetic spin-exchange interaction between the two Fe(III) ions within each molecule. The influence of halogen substituents in the bridging ligand on magnetic interactions between the metal ions of this kind of complexes is also discussed.