Ultra-high performance concrete (UHPC) is a type of cementitious material that has been specifically engineered to achieve exceptional mechanical properties and durability through optimized particle filling. However, the addition of steel fibers to the UHPC matrix creates a transitional region at the interface. Previous research has indicated that the use of silane coupling agents (SCA) on the surface of steel fibers is a promising approach for improving the bonding properties between the fibers and the matrix. This study aims to explore the impact of varying amounts of untreated steel fibers versus those that have undergone SCA treatment on the durability of UHPC. The findings indicate that treating steel fibers with SCA significantly narrows the pore space between the matrix and steel fibers, as well as enhances the production of hydration products on the steel fiber surface. Furthermore, this treatment facilitates the formation of a compact transition zone between the UHPC matrix and steel fibers. The electrochemical corrosion resistance, chloride ion penetration resistance, frost resistance, and sulfate erosion resistance of UHPC are all enhanced by this method. As a result, the durability of UHPC is significantly improved, making it an extremely promising avenue of research.
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