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Assessment of PCB-contaminated soil pretreatment remediation by hydroxypropyl-β-cyclodextrin (HP-β-CD)

Liu Xun, Ding Ning, Liu Hong, Chen Houwang

Archives of Environmental Protection

2020

Vol. 46, no. 1

53--61

The present study thoroughly evaluated the eff ect of hydroxypropyl-β-cyclodextrin (HP-β-CD) on eluting of Aroclor1242 (one kind of PCBs (polychlorinated biphenyls)) from contaminated soil. The factors that might aff ect eluting effi ciency including HP-β-CD concentration, contact time, eluting cycles, temperature, pH, salt content, humic acid, and ultrasonic were all tested to evaluate the PCBs eluting effi ciency by HP-β-CD. Results indicated that Aroclor1242 can be eluted eff ectively from soil by HP-β-CD solution, 81% of Aroclor1242 was eluted from soil by 50 g/L of HP-β-CD solution after three cycles eluting, and the eluting effi ciency was improved by increasing temperature and with ultrasonic. Furthermore, it was shown that the humic acid and extreme acidic/alkaline condition both decreased the eluting effi ciency. In addition, column eluting experiment was conducted to simulate the practical HP-β-CD eluting of Aroclor1242 from contaminated soil, 18% of the PCBs was eluted from the soil column by 10 g/L of HP-β-CD. Overall, the results indicated the high extract power of HP-β-CD toward PCBs polluted soil and potential use of HP-β-CD for in situ remediation of PCBs contaminated soils.