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Kinetics of homogeneous decomposition of asymmetric dialkyl peroxides

Baj S., Dawid M.

Polish Journal of Chemistry

1998

Vol. 72, nr 9

2151-2158

The homogeneous decomposition of various asymmetric dialkyl peroxides ROOR' (R=C6H5(CH3)2; R'=Et, Pr, Bu, Bu(i), Bu(s), Bu(t), n-heptyl, n-dodecyl and allyl) is examined by the measurement of autooxidation of isopropylbenzene in the presence of peroxides as initiators. Rate constants and activation parameters are determined and the size effect and type of alkyl group R' on stability of O-O bond is discussed.