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Chemia gazów szlachetnych

Łyczko K.

Wiadomości Chemiczne

2002

[Z] 56, 9-10

771-792

This paper summarizes the present state of knowledge of the chemistry of the noble gases. The methods used for preparation fluorides and other halides of the noble gases and their chemical reactivity are presented. The synthesis and properties of compounds containing Xe-O, Kr-O, Rn-O, Xe-N, Kr-N, Xe-C, Xe-Si, Xe-B and Xe-Cl bonds are described. This review paper also reports on exotic molecules HXY (X = Xe or Kr, and Y is a fragment of a molecule with a large electron affinity, i.e. halide or pseudohalide), which have recently been obtained in solid xenon or krypton matrices. Short-living metal carbonyl complexes containing Xe, Kr or Ar atoms and a compound with Au-Xe bonds are described. Information on the chemistry of elements 112 and 118, thought to be similar to the noble gases, is presented.