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1 Polish Journal of Chemical Technology

1 2016

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Graphene hydrogels with embedded metal nanoparticles as efficient catalysts in 4-nitrophenol reduction and methylene blue decolorization

Żelechowska K., Kondratowicz I., Gazda M.

Polish Journal of Chemical Technology

2016

Vol. 18, nr 4

47--55

Synthesis and characterization of the graphene hydrogels with three different metallic nanoparticles, that is Au, Ag and Cu, respectively is presented. Synthesized in a one-pot approach graphene hydrogels with embedded metallic nanoparticles were tested as heterogeneous catalysts in a model reaction of 4-nitrophenol reduction. The highest activity was obtained for graphene hydrogel with Cu nanoparticles and additional reaction of methylene blued degradation was evaluated using this system. The obtained outstanding catalytic activity arises from the synergistic effect of graphene and metallic nanoparticles. The hydrogel form of the catalyst benefits in the easiness in separation from the reaction mixture (for example using tweezers) and reusability.