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The chlorinated synthetic diamond surface interaction with C-nucleophiles

Korolkov V.V., Tarasevich B.N., Kulakova I.I., Lisichkin G.V.

Inżynieria Biomateriałów

2006

R. 9, nr 56-57

16-19

Several reactions of C-nucleophiles with the chlorinated surface of two types of diamond were implemented. Detonating nanodiamond "UDA-SF" and synthetic diamond "DALAN" have been employed in the above procedures. The incorporation of butyl and nitrile groups has been achieved. However the incorporating of phenyl groups via reaction with PhLi is still a problem. For the first time NMR-H1 spectroscopy of suspension was used for elucidating structure of grafting compounds was proposed.