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EN
We present herein studies of the influence of silyl protecting groups on regio- and stereoselectivity of glycosylation of partially protected (5-nitro-2-pyridyl) 1-thioglycosides with glycals.
EN
We present herein the totally stereoselective synthesis of (1--6)-alfa-linked di- and trisaccharides by addition of thioglucosides to D-glucals.
EN
Various glycols of the hexose and pentose series and different dideoxy hexopyranosides undergo smooth (Lewis) acid -catalyzed allylic rearrangement reactions to regioisometric deoxygenated disaccharide derivatives. The corresponding saturated components were obtained by hydrogenation. In addition, yhe neutral version of the Ferrier reaction employing pentenoyl glucal was tested, which gave rearrangement and addition products. Finally, certain glycols were condensed with differently functionalized glycols as aglyconic components to form disaccharide glycals.
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