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Spectrochemical Properties of Noncubic Transition Metal Complexes in Solution : XI. Angular Overlap Studies of Bis(oxalato)- and Bis(malonato)diaquachromate(III) Complexes in Aqueous Solution

Kurzak K.

Polish Journal of Chemistry

2000

Vol. 74, nr 3

331-347

Mixed ligands chromium(III) complexes with monodentate(water) and bidentate ligands: oxalic acid deprotonated or malonic acid have been synthesized, investigated and characterized structurally and spectroscopically. Their geometrical isomers have been studied spectrophotometrically in aqueous solution. The "poor" experimental contours were resolved into the component bands by Gaussian analysis.The effect of different bonding of the bidentate ligands upon the chromium(III) ion in aqueous solution was described and discussed.